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Gadolinium acetate is a white, crystalline powder with a slight acetic odor, commonly utilized in various industrial applications. It has a molecular formula of C6H9GdO6 and is characterized by its solubility in water and non-flammable nature, ensuring safe handling during its use. Gadolinium acetate is particularly recognized for its paramagnetic properties, making it a valuable substance in magnetic resonance imaging (MRI) and related applications.

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  • 16056-77-2 Structure
  • Basic information

    1. Product Name: GADOLINIUM ACETATE
    2. Synonyms: GADOLINIUM ACETATE;GADOLINIUM ACETATE HYDRATE;GADOLINIUM ACETATE TETRAHYDRATE;GADOLINIUM (III) ACETATE HYDRATE;GADOLINIUM(III) ACETATE TETRAHYDRATE;gadolinium(3+) acetate;GADOLINIUM ACETATE, 99.9%;Triacetic acid gadolinium salt
    3. CAS NO:16056-77-2
    4. Molecular Formula: 3C2H3O2*Gd
    5. Molecular Weight: 406.44
    6. EINECS: 240-204-9
    7. Product Categories: N/A
    8. Mol File: 16056-77-2.mol
    9. Article Data: 4
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 117.1 °C at 760 mmHg
    3. Flash Point: 40 °C
    4. Appearance: white to off-white crystals, possible acetic odor
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: GADOLINIUM ACETATE(CAS DataBase Reference)
    10. NIST Chemistry Reference: GADOLINIUM ACETATE(16056-77-2)
    11. EPA Substance Registry System: GADOLINIUM ACETATE(16056-77-2)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 16056-77-2(Hazardous Substances Data)

16056-77-2 Usage

Uses

Used in Electronics Industry:
Gadolinium acetate is used as a component in electronic devices for its unique magnetic properties, enhancing the performance and efficiency of these products.
Used in Ceramics Industry:
Gadolinium acetate is used as a material in the production of certain ceramics, where its magnetic properties contribute to the desired characteristics of the final product.
Used in Medical Imaging:
Gadolinium acetate is used as a contrast agent in magnetic resonance imaging (MRI) for enhancing the visibility of internal body structures, particularly in soft tissues. Its paramagnetic properties allow for better differentiation between healthy and diseased tissues, improving diagnostic accuracy.
Safety Precautions:
It is important to handle gadolinium acetate with care, as direct contact can cause eye and skin irritation. Additionally, ingestion or inhalation of the substance could be harmful, necessitating proper safety measures during its use.

Check Digit Verification of cas no

The CAS Registry Mumber 16056-77-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,0,5 and 6 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 16056-77:
(7*1)+(6*6)+(5*0)+(4*5)+(3*6)+(2*7)+(1*7)=102
102 % 10 = 2
So 16056-77-2 is a valid CAS Registry Number.
InChI:InChI=1/3C2H4O2.Gd/c3*1-2(3)4;/h3*1H3,(H,3,4);/q;;;+3/p-3

16056-77-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name GADOLINIUM ACETATE

1.2 Other means of identification

Product number -
Other names Gd(acetate)3

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16056-77-2 SDS

16056-77-2Relevant articles and documents

Photon upconversion in Yb3+-Tb3+ and Yb3+-Eu3+ activated core/shell nanoparticles with dual-band excitation

Dong, Hao,Sun, Ling-Dong,Wang, Ye-Fu,Xiao, Jia-Wen,Tu, Datao,Chen, Xueyuan,Yan, Chun-Hua

, p. 4186 - 4192 (2016)

Exploring novel lanthanide-activated upconversion nanoparticles with distinctive spectral fingerprints and emission lifetimes has long been a great concern for extended optical applications. Herein, we report the study of photon upconversion emissions in Yb3+-Tb3+ and Yb3+-Eu3+ activated nanoparticles with near-infrared excitation. In these nanoparticles, a high content of Yb3+ is required for the simultaneous excitation of two Yb3+ ions, yielding a Yb3+ dimer with a higher excited energy to upconvert photons onto Tb3+ and Eu3+. The optimum doping concentration of Yb3+ ions for Yb3+-Tb3+ and Yb3+-Eu3+ pairs was determined to be 80% and 60%, respectively, which are much higher than that of Yb3+-Er3+/Tm3+ pairs. Notably, the upconversion emission lifetime of the as-prepared nanoparticles was prolonged to 2.3 ms (Tb3+) and 4.0 ms (Eu3+), respectively. Through the epitaxial growth of a Nd3+ doped shell layer, the upconversion emissions of Tb3+ and Eu3+ were intensified 25-fold. At the same time, an extra excitation band in the shorter near-infrared region from Nd3+ at 808 nm was achieved. Moreover, the emissions of Tm3+ were employed to compensate for those of Tb3+ and Eu3+ for multicolor emissions. These results highlight the upconversion emissions of Tb3+ and Eu3+ for potential multicolor imaging and multiplexed detection applications.

Upconversion luminescence in sub-10 nm β-NaGdF4:Yb3+,Er3+ nanoparticles: An improved synthesis in anhydrous ionic liquids

Tessitore, Gabriella,Mudring, Anja-Verena,Kr?mer, Karl W.

, p. 34784 - 34792 (2019)

Sub-10 nm β-NaGdF4:18% Yb3+,2% Er3+ nanoparticles were synthesized in ethylene glycol and various ionic liquids under microwave heating. The products were characterized by powder X-ray diffraction, electron microscopy, and upconversion (UC) luminescence spectroscopy. After Yb3+ excitation at 970 nm, Er3+ ions are excited by energy transfer upconversion and show the typical green and red emission bands. The UC luminescence intensity was optimized with respect to reactant concentrations, solvents, and reaction temperature and time. The strongest UC emission was achieved for sub-20 nm core-shell nanoparticles which were obtained in the ionic liquid diallyldimethylammonium bis(trifluoromethanesulfonyl)amide from a two-step synthesis without intermediate separation. Strictly anhydrous reaction conditions, a high fluoride/rare earth ion ratio, and a core-shell structure are important parameters to obtain highly luminescent nanoparticles. These conditions reduce non-radiative losses due to defects and high energy acceptor modes of surface ligands. A low power excitation of the core-shell particles by 70 mW at 970 nm results in an impressive UC emission intensity of 0.12% compared to the bulk sample.

Comparative studies of structure, spectroscopic properties and intensity parameters of tetragonal rare earth vanadate nanophosphors doped with Eu(III)

Grzyb, Tomasz,Szczeszak, Agata,Shyichuk, Andrii,Moura, Renaldo Tenorio,Neto, Albano Neto Carneiro,Andrzejewska, Nina,Malta, Oscar Loureiro,Lis, Stefan

, p. 459 - 472 (2018)

Hydrothermal method was applied in order to synthesize nanocrystalline YVO4, LaVO4 and GdVO4 materials doped with Eu3+ ions. The conditions of synthesis were chosen to allow control of the process based on precipitation reaction in an autoclave, at elevated temperature and pressure. The prepared materials crystallized as single phase spherical-like nanocrystals of the tetragonal I41/amd structure. The average size of the particles was in the range of 7–10 nm in the YVO4- and GdVO4-based products and about 32 nm when LaVO4 was the host compound. The excitation spectra of the materials prepared revealed a broad and intense band in the UV region. The band resulted from charge transfer phenomena: excitation of the VO43+ groups was followed by the energy transfer to Eu3+ ions. Intense, red emission of the samples was a result of electronic transitions in Eu3+ dopant ions. The theoretical Judd-Ofelt intensity parameters Ωλ, obtained using the novel approach to the calculation of Eu-O bond stretching force constant and subsequently charge factors, were compared to the experimental Ωλ. Forced electric dipole part of Ωλ was calculated from scratch (using Eu3+ coordination geometry in REVO4 from DFT calculations), while a single parameter in the dynamic coupling part was fitted to the experimental data. The issues related to the force constant calculation are discussed. Crucial influence of crystal lattice distortions on Ωλ and Eu3+ emission intensities of the materials was shown.

Preparation of REFeAsO1-xFx (R E=Sm and Gd) superconductors at a relatively low temperature

Cui,Chen,Cheng,Yang,Wang,Li,Zhao

, p. 449 - 452 (2011/07/07)

A series of the SmFeAsO1-xFx and GdFeAsO 1-xFx (x=0.05, 0.1, 0.15, 0.2, 0.25) samples have been prepared using nano-scaled ReF3 as the fluorine resource at a relatively low temperature. The samples have been sintered at 1100 and 1120 °C for SmFeAsO1-xFx and GdFeAsO1-xF x, respectively. These temperatures are at least 5060° lower than other previous reports. All of the so-prepared samples possess a tetragonal ZrCuSiAs-type structure. Dramatically supression of the lattice parameters and increase in Tc proved that this low temperature process was more effective to introduce fluorine into REFeAsO. Superconducting transition appeared at 39.5 K for SmFeAsO1-xFx with x=0.05 and at 22 K for GdFeAsO1-xFx with x=0.1. The highest Tc was detected to be 54 K in SmFeAsO0.8F0.2 and 40.2 K in GdFeAsO0.75F0.25. The use of the nano-scaled ReF3 compounds has improved the efficiency of the present low temperature method in synthesizing the fluorine-doped iron-based superconductors.

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