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159614-36-5

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  • 159614-36-5 Structure

  • Basic information

    1. Product Name: Boronic acid, [2,2'-bipyridine]-4,4'-diylbis-
    2. Synonyms: Boronic acid, [2,2'-bipyridine]-4,4'-diylbis-;[2,2'-Bipyridine]-4,4'-diylbis-boronic acid;[2,2'-Bipyridine]-4,4'-diyldiboronic acid
    3. CAS NO:159614-36-5
    4. Molecular Formula: C10H10B2N2O4
    5. Molecular Weight: 243.8194
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 159614-36-5.mol
    9. Article Data: 1

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 604.5±65.0 °C(Predicted)
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: 1.43±0.1 g/cm3(Predicted)
    6. Refractive Index: N/A
    7. Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
    8. Solubility: N/A
    9. PKA: 6.73±0.10(Predicted)
    10. CAS DataBase Reference: Boronic acid, [2,2'-bipyridine]-4,4'-diylbis-(CAS DataBase Reference)
    11. NIST Chemistry Reference: Boronic acid, [2,2'-bipyridine]-4,4'-diylbis-(159614-36-5)
    12. EPA Substance Registry System: Boronic acid, [2,2'-bipyridine]-4,4'-diylbis-(159614-36-5)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 159614-36-5(Hazardous Substances Data)

159614-36-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 159614-36-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,9,6,1 and 4 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 159614-36:
(8*1)+(7*5)+(6*9)+(5*6)+(4*1)+(3*4)+(2*3)+(1*6)=155
155 % 10 = 5
So 159614-36-5 is a valid CAS Registry Number.

159614-36-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name [2-(4-boronopyridin-2-yl)pyridin-4-yl]boronic acid

1.2 Other means of identification

Product number -
Other names [2,2'-Bipyridine]-4,4'-diyldiboronic acid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:159614-36-5 SDS

159614-36-5Synthetic route

4,4'-dibromo-2,2'-bipyridine
18511-71-2

4,4'-dibromo-2,2'-bipyridine

Triisopropyl borate
5419-55-6

Triisopropyl borate

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

Conditions
ConditionsYield
With water In tetrahydrofuran -90°C; then hydrolysis;
D-Fructose
57-48-7

D-Fructose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O6

C10H10B2N2O4*C6H12O6

Conditions
ConditionsYield
complex formation;
D-xylose
58-86-6

D-xylose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C5H10O5

C10H10B2N2O4*C5H10O5

Conditions
ConditionsYield
complex formation;
D-Mannose
3458-28-4

D-Mannose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O6

C10H10B2N2O4*C6H12O6

Conditions
ConditionsYield
complex formation;
D-ribose
50-69-1

D-ribose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C5H10O5

C10H10B2N2O4*C5H10O5

Conditions
ConditionsYield
complex formation;
D-Fucose
3615-37-0

D-Fucose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O5

C10H10B2N2O4*C6H12O5

Conditions
ConditionsYield
complex formation;
D-glucose
50-99-7

D-glucose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O6

C10H10B2N2O4*C6H12O6

Conditions
ConditionsYield
complex formation;
D-talose
2595-98-4

D-talose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O6

C10H10B2N2O4*C6H12O6

Conditions
ConditionsYield
complex formation;
D-Galactose
59-23-4

D-Galactose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O6

C10H10B2N2O4*C6H12O6

Conditions
ConditionsYield
complex formation;
L-glucose
921-60-8

L-glucose

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

C10H10B2N2O4*C6H12O6

C10H10B2N2O4*C6H12O6

Conditions
ConditionsYield
complex formation;
2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

Cellobiose
13360-52-6

Cellobiose

C12H22O11*C10H10B2N2O4

C12H22O11*C10H10B2N2O4

Conditions
ConditionsYield
complex formation;
cobalt(II) acetate
71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7

cobalt(II) acetate

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

Co[BO(OH)C5NH3C5NH3BO(OH)]3(3-)

Co[BO(OH)C5NH3C5NH3BO(OH)]3(3-)

Conditions
ConditionsYield
With oxygen In methanol; water dissolution opf sugar and ligand at pH 7.4 in water, mixing with Co(OAc)2 ine H2O-MeOH at -30 to 20°C, stirring at this temp. for 2 days,bubbling O2 for 48 h; HPLC, enantiomeric excess studied;
cobalt(II) acetate
71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7

cobalt(II) acetate

2,2'-bipyridine-4,4'-diboronic acid
159614-36-5

2,2'-bipyridine-4,4'-diboronic acid

Co[BO(OH)C5NH3C5NH3BO(OH)]3(3-)

Co[BO(OH)C5NH3C5NH3BO(OH)]3(3-)

Conditions
ConditionsYield
With oxygen In methanol; water dissolution opf sugar and ligand at pH 7.4 in water, mixing with Co(OAc)2 ine H2O-MeOH at -30 to 20°C, stirring at this temp. for 2 days,bubbling O2 for 48 h; HPLC, enantiomeric excess studied;

159614-36-5Downstream Products

159614-36-5Relevant articles and documents

Sugar-Assisted Chirality Control of Tris(2,2'-bipyridine)-Metal Complexes

Nakashima, Kazuaki,Shinkai, Seiji

, p. 1267 - 1270 (2007/10/02)

2,2'-Bipyridine-4,4'-diboronic acid (2), a 2,2'-bipyridine derivative with sugar-binding sites was synthesized.The Δ vs.A chirality of the Fe2+*23 complex was selectively generated in correlation with the absolute configuration of added saccharides.

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