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  • 158924-90-4 Structure
  • Basic information

    1. Product Name: N,N-diallylaniline(trimethylphosphine)nickel(0)
    2. Synonyms:
    3. CAS NO:158924-90-4
    4. Molecular Formula:
    5. Molecular Weight: 308.026
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 158924-90-4.mol
    9. Article Data: 1
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: N,N-diallylaniline(trimethylphosphine)nickel(0)(CAS DataBase Reference)
    10. NIST Chemistry Reference: N,N-diallylaniline(trimethylphosphine)nickel(0)(158924-90-4)
    11. EPA Substance Registry System: N,N-diallylaniline(trimethylphosphine)nickel(0)(158924-90-4)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 158924-90-4(Hazardous Substances Data)

158924-90-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 158924-90-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,5,8,9,2 and 4 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 158924-90:
(8*1)+(7*5)+(6*8)+(5*9)+(4*2)+(3*4)+(2*9)+(1*0)=174
174 % 10 = 4
So 158924-90-4 is a valid CAS Registry Number.

158924-90-4Relevant articles and documents

Chelating Coordination of Di- and Triallylamines: Syntheses and NMR Studies of Trimethylphosphane Nickel and Cobalt Complexes

Klein, Hans-Friedrich,Helwig, Michael,Braun, Siegmar

, p. 1563 - 1568 (2007/10/02)

16-Electron complexes of zerovalent nickel with diallylamines, NiL and 2CH22 (4), were synthesized by reduction of NiCl2L2 with magnesium in tetrahydrofuran.NiCl(ν3-C3H5)2 (5), a low-yield byproduct, was also obtained in high yield from NiL4 and C3H5Cl.With triallylamine as starting material complexes NiL were generated exhibiting ν6- and ν4-olefin coordination, respectively. 17-electron cobalt(0) compounds Co(PMe3)2 (8, 9: R = CH3, C6H5) were obtained by reaction of Co(cyclo-C5H8)(PMe3)3 with the corresponding diallylamine, while CoR(PMe3)4 (R = CH3, C6H5) reacted with N,N-diallylaniline to give diamagnetic Co3-C3H4)(ν2-C3H5)NC6H5>(PMe3)2, (10).The coordination mode of allylic functions was deduced from IR, ESR and especially 1H- and 13C-NMR spectra including 2D-NMR experiments. - Key Words: Allylamine nickel complexes / Allylamine cobalt complexes / 2D NMR, TOCSY

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