157794-54-2Relevant articles and documents
Synthesis, crystal structures and reactivity towards dioxygen of copper(I) complexes with tripodal aliphatic amine ligands
Will, Janine,Würtele, Christian,Becker, Jonathan,Walter, Olaf,Schindler, Siegfried
, p. 448 - 454 (2019)
Copper(I) complexes of the tripodal, tetradentate, aliphatic ligands Me3tren (Me3tren = tris-(2-methylaminoethyl)amine), Isoprop3tren (Isoprop3tren = tris-(2-isopropylaminoethyl)amine) and Me3isoprop3tren (Me3isoprop3tren = tris-(2-isopropylmethylaminoethyl)amine) of the Tren-family (Tren = tris(2-aminoethyl)amine) were prepared and structurally characterized. Furthermore, they were reacted in solution at low temperatures with dioxygen. All complexes formed a short-lived superoxido intermediate complex that could be observed using low temperature stopped-flow techniques prior to consecutive reactions. However, the superoxido complexes were too reactive to allow isolation and full characterization in contrast to previous work.
Synthesis of new proazaphosphatranes and their application in organic synthesis
Kisanga, Philip B.,Verkade, John G.
, p. 467 - 475 (2007/10/03)
We report herein the synthesis of the new proazaphosphatrane strong bases P(RNCH2CH2)3N (R=Me3CCH2, Me2CHCH2) and P(HNCH2CH2)2NCH2CH2 N-i-Pr (1g). The new azaphosphatranes [HP(RNCH2CH2)3N]Cl (R=Me3CCH2, Me2CHCH2) have P-Nax distances of 2.047 and 1.958 ?, respectively. We also report the synthesis of the tetramine precursor proazaphosphatrane 1g [namely, (H2NCH2CH2) 2NCH2CH2NH-i-Pr] in 41% yield and the use of a complexation-extraction technique to separate it from a mixture containing the di- and tri-isopropyl substituted analogs. Using a 31P NMR technique, we report the pKa value for 1gH+ (34.49). The catalytic properties of three bases P(RNCH2CH2)3N (R=i-Pr, Piv, i-Bu) are compared in the synthesis of several β-hydroxy nitriles, β-nitroalkanols, α,β-unsaturated esters and for the Michael addition of allyl alcohol to α,β-unsaturated ketones.