154545-22-9Relevant articles and documents
Carbonyl Oxide Chemistry. Part 2. Substituent and Solvent Effects on the Chemical Behaviour of Carbonyl Oxides
Iesce, M. Rosaria,Cermola, Flavio,Graziano, M. Liliana,Scarpati, Rachele
, p. 147 - 152 (2007/10/02)
Comparison of the behaviour in polar and apolar solvents at various concentrations of the monoaryl carbonyl oxides 1 bearing an electron-withdrawing or an electron-donating group, respectively, on the aryl substituent is reported.The results are consistent with the conversion pathways reported in Scheme 1 and show that the electron-donating group increases the intramolecular oxygen-transfer potential of the system.It is also proposed that under some experimental conditions the carbonyl oxides so substituted mainly isomerize into dioxiranes 11.