15025-74-8

Basic information

• Product Name: tris(2,2'-bipyridyl)-Fe(II) complex
• Synonyms: tris(2,2'-bipyridyl)-Fe(II) complex;Iron(2+),tris(2,2'-bipyridine-kN1,kN1')-, (OC-6-11)-
• CAS NO: 15025-74-8
• Molecular Formula: C₃₀H₂₄FeN₆
• Molecular Weight: 524.39676
• Mol File: 15025-74-8.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 272.5°Cat760mmHg
• Flash Point: 107.2°C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: tris(2,2'-bipyridyl)-Fe(II) complex(CAS DataBase Reference)
• NIST Chemistry Reference: tris(2,2'-bipyridyl)-Fe(II) complex(15025-74-8)
• EPA Substance Registry System: tris(2,2'-bipyridyl)-Fe(II) complex(15025-74-8)

Safety Data

• Hazardous Substances Data: 15025-74-8(Hazardous Substances Data)

Upstream product

• 22541-53-3 cobalt(II) 
• 19229-76-6 iron(III) 
• 83771-90-8 Rh(CNC₆H₅)4⁽¹⁺⁾*ClO₄^(1-)=[Rh(CNC₆H₅)4]ClO₄ 
• 18661-69-3 tris(2,2'-bipyridine)iron(III) ion 
• 34178-82-0 C₂₈H₄₄N₄Rh⁽¹⁺⁾ 
• 61754-49-2 C₃₆H₃₆N₄Rh⁽¹⁺⁾ 
• 70443-06-0 C₄₀H₄₄N₄Rh⁽¹⁺⁾ 
• 83771-93-1 Rh(CNC₆H₁₁)4⁽¹⁺⁾*ClO₄^(1-)=[Rh(CNC₆H₁₁)4]ClO₄ 
• 70443-07-1 Rh(CNC₆H₂(CH₃)3)4⁽¹⁺⁾*ClO₄^(1-)=[Rh(CNC₆H₂(CH₃)3)4]ClO₄ 
• 43093-67-0 Rh(CNC₆H₄CH₃)4⁽¹⁺⁾*ClO₄^(1-)=[Rh(CNC₆H₄CH₃)4]ClO₄ 
• 83771-92-0 [Rh(C₆H₅CH₂NC)4]⁽¹⁺⁾*ClO₄^(1-)=[Rh(C₆H₅CH₂NC)4]ClO₄ 
• 83771-95-3 [Rh((CH₃)3C₆H₂NC)2(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh((CH₃)3C₆H₂NC)2(P(C₆H₅)3)2]ClO₄ 
• 84470-67-7 tetrakis(p-chlorophenyl isocyanide)rhodium(I) perchlorate 
• 55332-26-8 [Rh(CH₃OC₆H₄NC)2(P(C₆H₅)3)2]⁽¹⁺⁾*ClO₄^(1-)=[Rh(CH₃OC₆H₄NC)2(P(C₆H₅)3)2]ClO₄ 

Downstream Products

• 18661-69-3 tris(2,2'-bipyridine)iron(III) ion 
• 7782-77-6 cis-nitrous acid 
• 366-18-7 [2,2]bipyridinyl 
• 7439-89-6 iron(II) 
• 51383-17-6 bis(2,2'-bipyridine)(2,2'-bipyridine^(1-))iron(II)⁽¹⁺⁾ 
• 75-07-0 acetaldehyde 
• 15552-69-9 iron(II) bis(2,2'-bipyridine) 

Relevant articles and documents

Cyclic Voltammetry of Rh(I) Complexes and the Oligomers. A Correlation between the Anodic Peak Potentials and the Rate Constants for the Electron Transfer Reactions with Inorganic Oxidants

The cyclic voltammogram of a CH3CN solution of + exhibits three anodic current peaks which correspond to the oxidations of the monomer, the dimer, and the trimer, with no cathodic wave on the reverse scan.The anodic peak potentials Epox in such irreversible cyclic voltammograms were determined for various Rh(I) monomers and the oligomers such as +, 2+, 2+, 2+, 3+, and 4+ (R=p-MeOC6H4 and Ph, etc; dppm=bis(diphenylphosphino)methane, dicp=1,3-diisocyanopropane).The anodic peak potentials Epox vary mainly with the degree of oligomerization of the Rh(I) complexes, decreasing in the order monomer > dimer > trimer > tetramer, in parallel with the energies of the highest occupied molecular orbitals EHOMO.It has been found that the Epox values are linearly correlated with logarithm of the rate constants for the electron transfer reactions with inorganic oxidants such as 3+ and 3+ (bpy=2,2'-bipyridine) in the context of the Marcus theory as expected when the standard oxidation potentials E0ox would be used.It is thus suggested that the anodic peak potentials of the Rh(I) complexes in the irreversible system can be used as the standard oxidation potentials as far as the relative values are concerned.