149529-74-8Relevant articles and documents
A direct route to medium and large cyclic amines from aminoalkenes
Bergmann, David J.,Campi, Eva M.,Jackson, W. Roy,Patti, Antonio F.,Saylik, Dilek
, p. 5597 - 5600 (1999)
Rhodium-catalysed reactions of aminoalkenes with H2/CO give cyclic amines with a range of medium and large ring sizes in yields up to 85%. High regioselectivity for non-branched products can be obtained when BIPHEPHOS is used as a ligand in the
Metal Acetylide Elimination: The Key Step in the Cascade Decomposition and Transformation of Metalated Propargylamines
Flynn, Matthew T.,Blair, Victoria L.,Andrews, Philip C.
supporting information, p. 1225 - 1228 (2018/04/30)
Metal acetylide elimination facilitates a novel one-pot cascade metalation and elimination/addition route to a series of unsymmetrical secondary amines from the reaction of secondary propargylamines with organometallic reagents. Spectroscopic evidence suggests a dimetalated amido intermediate rather than an allene.
