1422122-96-0Relevant articles and documents
Multifunctionalization of alkenes via aerobic oxynitration and sp 3 C-H oxidation
Taniguchi, Tsuyoshi,Sugiura, Yuki,Hatta, Takashi,Yajima, Atsushi,Ishibashi, Hiroyuki
supporting information, p. 2198 - 2200 (2013/03/29)
A method for direct functionalization of three positions including an unactivated C-H bond of aliphatic alkenes using tert-butyl nitrite and molecular oxygen to give γ-lactols has been developed. The present reaction proceeds through a sequence of radical processes involving oxynitration followed by aerobic oxidation of an sp3 C-H bond. This multifunctionalization reaction requires neither metallic reagents nor photolysis and proceeds under mild conditions.