1401234-51-2Relevant articles and documents
A highly efficient, blue-phosphorescent device based on a wide-bandgap host/FIrpic: Rational design of the carbazole and phosphine oxide moieties on tetraphenylsilane
Liu, He,Cheng, Gang,Hu, Dehua,Shen, Fangzhong,Lv, Ying,Sun, Guannan,Yang, Bing,Lu, Ping,Ma, Yuguang
experimental part, p. 2830 - 2836 (2012/09/11)
A new series of wide-bandgap materials, 4-dipenylphosphine oxide-4'-9H-carbazol-9-yl-tetraphenylsilane (CSPO), 4-diphenylphosphine oxide-4',4″-di(9H-carbazol-9-yl)-tetraphenylsilane (pDCSPO), 4-diphenylphosphine oxide -4'-[3-(9H-carbazol-9-yl)-carbazole-9-yl]- tetraphenylsilane (DCSPO), 4-diphenylphosphine oxide-4',4″,4″'- tri(9H-carbazol-9-yl)-tetraphenylsilane (pTCSPO) and 4-diphenylphosphine oxide -4'-[3,6-di(9H-carbazol-9-yl)-9H-carbazol-9-yl]-tetraphenylsilane (TCSPO), containing different ratios and linking fashions of p-type carbazole units and n-type phosphine oxide units, are designed and obtained. DCSPO is the best host in FIrpic-doped devices for this series of compounds. By utilizing DCzSi and DPOSi as hole- and electron-transporting layers, a high EQE of 27.5% and a maximum current efficiency of 49.4 cd A-1 are achieved in the DCSPO/FIrpic doped device. Even at 10 000 cd m-2, the efficiencies still remain 41.2 cd A-1 and 23.0%, respectively.
