139021-69-5

Basic information

• Product Name: 3-Cyclohexene-1-methanol, a-(1-methylethenyl)-
• CAS NO: 139021-69-5
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Mol File: 139021-69-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-Cyclohexene-1-methanol, a-(1-methylethenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Cyclohexene-1-methanol, a-(1-methylethenyl)-(139021-69-5)
• EPA Substance Registry System: 3-Cyclohexene-1-methanol, a-(1-methylethenyl)-(139021-69-5)

Safety Data

• Hazardous Substances Data: 139021-69-5(Hazardous Substances Data)

Upstream product

• 557-93-7 2-bromoprop-1-ene 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 13291-18-4 isopropenylmagnesium bromide 

Downstream Products

• 1449104-46-4 (E)-5-(cyclohex-3-enyl)-4-methylpent-4-enal 
• 1449104-71-5 (E)-5-(cyclohex-3-enyl)-4-methylpent-4-en-1-ol 
• 1449104-69-1 (E)-ethyl 5-(cyclohex-3-enyl)-4-methylpent-4-enoate 

Relevant articles and documents

Stereoselective Dehydroxyboration of Allylic Alcohols to Access (E)-Allylboronates by a Combination of C-OH Cleavage and Boron Transfer under Iron Catalysis

Iron-catalyzed direct SN2′ dehydroxyboration of allylic alcohols has been developed to access (E)-stereoselective allylboronates. Allylic alcohols with diverse structures and functional groups, especially derived from natural products, underwent smooth transformation. The six-membered ring transition state formed by allylic alcohols and iron-boron intermediate was indicated to be the key component involved in transfer of the boron group, activation of the C-OH bond, and control of the stereoselectivity.