13829-13-5

Basic information

• Product Name: Benzamide, N-cyano-N-methyl- (8CI,9CI)
• Synonyms: Benzamide, N-cyano-N-methyl- (8CI,9CI)
• CAS NO: 13829-13-5
• Molecular Formula: C₉H₈N₂O
• Molecular Weight: 160.17262
• Product Categories: AMIDE
• Mol File: 13829-13-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzamide, N-cyano-N-methyl- (8CI,9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, N-cyano-N-methyl- (8CI,9CI)(13829-13-5)
• EPA Substance Registry System: Benzamide, N-cyano-N-methyl- (8CI,9CI)(13829-13-5)

Safety Data

• Hazardous Substances Data: 13829-13-5(Hazardous Substances Data)

Upstream product

• 19411-70-2 N-tert-butyl-N'-methylcarbodiimide 
• 98-88-4 benzoyl chloride 
• 556-61-6 methyl thioisocyanate 

Downstream Products

• 1404074-00-5 N-benzoyl-N’-methyl-S-phenylisothiourea 
• 1404074-00-5 C₁₅H₁₄N₂OS 
• 1404074-01-6 N-benzoyl-N’-methyl-S-(4-chlorophenyl)isothiourea 
• 1404074-01-6 C₁₅H₁₃ClN₂OS 
• 1404074-26-5 N-((4-(-2-benzoyl-3-methylguanidino)butyl)-1-methyl-5-oxoimidazolidin-2-ylidene)benzamide 
• 1404074-14-1 N-benzoyl-N’-benzyl-N”-methylguanidine 

Relevant articles and documents

Rearrangements of N-acyl isothioureas. alternate access to acylguanidines from cyanamides

We report a tin-free one-pot radical approach to the synthesis of N-acyl isothioureas and acylguanidines from N-acyl cyanamides. Photoactivated reduction of aromatic disulfides in the presence of Huenig's base results in hydrothiolation of the cyanamide moiety, followed by spontaneous 1,3-migration of the acyl group. Onward reaction of the isothioureas obtained with amines led to the corresponding N-acylguanidines, where the acyl group is attached to the nitrogen atom formerly at the cyano-end of the starting material.