1380112-97-9

Basic information

• Product Name: 1,3,4,5-tetrahydro-2,4-benzoxazepine-1,5-dione
• Synonyms: 1,3,4,5-tetrahydro-2,4-benzoxazepine-1,5-dione
• CAS NO: 1380112-97-9
• Molecular Weight: 177.159
• Mol File: 1380112-97-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,4,5-tetrahydro-2,4-benzoxazepine-1,5-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,4,5-tetrahydro-2,4-benzoxazepine-1,5-dione(1380112-97-9)
• EPA Substance Registry System: 1,3,4,5-tetrahydro-2,4-benzoxazepine-1,5-dione(1380112-97-9)

Safety Data

• Hazardous Substances Data: 1380112-97-9(Hazardous Substances Data)

Upstream product

• 136918-14-4 phthalimide 
• 17564-64-6 N-(chloromethyl)phthalimide 
• 203255-55-4 2-(iodomethyl)isoindoline-1,3-dione 
• 118-29-6 2-(hydroxymethyl)-1H-isoindole-1,3(2H)-dione 

Relevant articles and documents

Aminomethylation of Michael acceptors: Complementary radical and polar approaches mediated by dialkylzincs

Phtalimidomethyl iodide and substituted maleimidomethyl iodide were used as radical precursors in dialkylzinc-mediated radical addition to diethyl fumarate. The reactions led stereoselectively to functionalized pyrrolizidines. The radical mechanism was supported by spin-trapping experiments and rationalized by theoretical calculations. Radical additions, on the one hand, and carbozincation followed by transmetalation with copper(I), on the other, were shown to be complementary methods to achieve the formal aminomethylation of activated unsaturated compounds. Copyright