137524-63-1

Basic information

• Product Name: 2,2-Dichloro-1-phenyl-2-phenylsulfanyl-ethanone
• Synonyms: 2,2-Dichloro-1-phenyl-2-phenylsulfanyl-ethanone
• CAS NO: 137524-63-1
• Molecular Weight: 297.205
• Mol File: 137524-63-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,2-Dichloro-1-phenyl-2-phenylsulfanyl-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Dichloro-1-phenyl-2-phenylsulfanyl-ethanone(137524-63-1)
• EPA Substance Registry System: 2,2-Dichloro-1-phenyl-2-phenylsulfanyl-ethanone(137524-63-1)

Safety Data

• Hazardous Substances Data: 137524-63-1(Hazardous Substances Data)

Upstream product

• 113446-38-1 β,β-dichloro-α-trimethylsilyloxystyrene 
• 931-59-9 benzenesulfenyl chloride 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 

Downstream Products

• 94123-66-7 S-phenyl 2-oxo-2-phenylethanethioate 
• 15206-55-0 methyl 2-oxo-2-phenylacetate 

Relevant articles and documents

REACTIONS OF HALOGEN-CONTAINING O-SILYLATED ENOLATES. VII. REACTIONS OF HALOGEN-CONTAINING O-SILYLATED ENOLATES WITH SULFENYL CHLORIDES

Reactions of halogen-containing O-silylated enolates with arenesulfenyl chlorides lead to aldehydes and ketones containing halogen atoms and an arylthio group in the α position.Reaction between these reactants is accelerated by change from electron-acceptor to electron-donor substituents both in the silyl ether and in the sulfenyl chloride and by the use of polar solvents.For silyl ethers of enols of aldehydes reaction with sulfenyl chlorides proceeds through the stage of the formation of a halogen-containing 2-arylthio-1-halo-1-(trimethylsiloxy)alkane, which is an intermediate 1,2-addition product.