1361029-78-8

Basic information

• Product Name: (S)-methyl 2-{[(benzyloxy)carbonyl]amino}-3-(2-methyl-3-oxo-3H-pyrrolo[1,2-a]indol-9-yl)propanoate
• Synonyms: (S)-methyl 2-{[(benzyloxy)carbonyl]amino}-3-(2-methyl-3-oxo-3H-pyrrolo[1,2-a]indol-9-yl)propanoate
• CAS NO: 1361029-78-8
• Molecular Weight: 418.449
• Mol File: 1361029-78-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-methyl 2-{[(benzyloxy)carbonyl]amino}-3-(2-methyl-3-oxo-3H-pyrrolo[1,2-a]indol-9-yl)propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-methyl 2-{[(benzyloxy)carbonyl]amino}-3-(2-methyl-3-oxo-3H-pyrrolo[1,2-a]indol-9-yl)propanoate(1361029-78-8)
• EPA Substance Registry System: (S)-methyl 2-{[(benzyloxy)carbonyl]amino}-3-(2-methyl-3-oxo-3H-pyrrolo[1,2-a]indol-9-yl)propanoate(1361029-78-8)

Safety Data

• Hazardous Substances Data: 1361029-78-8(Hazardous Substances Data)

Upstream product

• 1361029-77-7 (S)-methyl 2-{[(benzyloxy)carbonyl]amino}-3-(1-methacryloyl-1H-indol-3-yl)propanoate 
• 7524-52-9 (S)-tryptophan methyl ester hydrochloride 
• 2717-76-2 (S)-N-benzyloxycarbonyl-L-tryptophan methyl ester 
• 501-53-1 benzyl chloroformate 

Relevant articles and documents

Aerobic palladium(II)-catalyzed 5-endo-trig cyclization: An entry into the diastereoselective C-2 alkenylation of indoles with tri- and tetrasubstituted double bonds

The endo trick: An endo ring closure onto the trigonal β carbon atom of α,β-unsaturated acceptors that are tethered to the indole nitrogen atom followed by amide cleavage enables the diastereoselective C-2 alkenylation of indoles with fully substituted double bonds. The carboxy group functions as a synthetically useful temporary tether (see scheme). Copyright