13559-66-5

Basic information

• Product Name: 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE OXIME
• Synonyms: 2,7,7-trimethyl-bicyclo(2.2.1)heptan-2-onoxime;2-bornanone,oxime;2-Camphanone oxime;2-camphanoneoxime;Bicyclo[2.2.1]heptan-2-one, 1,7,7-trimethyl-, oxime;Camphor, d-oxime;Kampferoxim;AKOS 92216
• CAS NO: 13559-66-5
• Molecular Formula: C₁₀H₁₇NO
• Molecular Weight: 167.25
• EINECS: 236-945-2
• Mol File: 13559-66-5.mol
• Article Data: 16

Chemical Properties

• Melting Point: 110 °C
• Boiling Point: 243°Cat760mmHg
• Flash Point: 136.5°C
• Appearance: /
• Density: 1.14g/cm³
• Vapor Pressure: 0.0109mmHg at 25°C
• Refractive Index: 1.568
• CAS DataBase Reference: 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE OXIME(CAS DataBase Reference)
• NIST Chemistry Reference: 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE OXIME(13559-66-5)
• EPA Substance Registry System: 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE OXIME(13559-66-5)

Safety Data

• Hazardous Substances Data: 13559-66-5(Hazardous Substances Data)

Usage

General Description

1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one oxime is a chemical compound with the molecular formula C10H17NO. It is commonly used as a flavoring agent in the food industry and as a fragrance in the perfume industry. 1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPTAN-2-ONE OXIME is also known for its potential use as a chemoattractant for insect pests, particularly the red palm weevil. It has a bicyclic structure and a ketone functional group, which makes it versatile for various chemical reactions and applications. However, it is important to handle this compound with caution, as it can be toxic when ingested or absorbed through the skin.

InChI:InChI=1/C10H17NO/c1-9(2)7-4-5-10(9,3)8(6-7)11-12/h7,12H,4-6H2,1-3H3/b11-8+

Upstream product

• 33081-41-3 1,7,7-Trimethyl-2-nitrobicyclo<2.2.1>heptane 
• 76-22-2 Camphor 
• 2792-42-9 (R,R)-camphor oxime 
• 13181-22-1 O-(2',4'-dinitrophenyl) 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one oxime 
• 141-43-5 ethanolamine 
• 123-75-1 pyrrolidine 
• 108-91-8 cyclohexylamine 
• 110-89-4 piperidine 
• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 

Downstream Products

• 314238-36-3 1,7,7-Trimethyl-bicyclo[2.2.1]heptan-2-one O-oxiranylmethyl-oxime 
• 15373-31-6 α-campholenonitrile 
• 73886-28-9 2-(propargyloxyimino)-1,7,7-trimethyl-bicyclo[2,2,1]heptane 
• 136206-68-3 C₂₂H₂₆NOP 
• 13180-60-4 1,7,7-Trimethyl-bicyclo[2.2.1]heptan-2-one O-(5-chloro-2,4-dinitro-phenyl)-oxime 
• 31180-79-7 camphor nitrimine 
• 28154-30-5 (1S,4S)-2-Chloro-1,7,7-trimethyl-2-nitro-bicyclo[2.2.1]heptane 
• 1152-98-3 C₁₇H₂₁NO₂ 
• 73886-28-9 (+/-)-2-(propargyloxyimino)-1,7,7-trimethyl-bicyclo[2,2,1]-heptane 
• 72445-71-7 N-(β-Campholenyl)-p-chlorbenzylidenimin 
• 72445-79-5 β-Campholenyl-N-(2,3-dichlorphenyl)urethan 
• 74957-38-3 α-Campholenyl-N-(2,3-dichlorphenyl)urethan 
• 72445-69-3 1-(4-Chloro-3-methyl-phenyl)-3-[2-(2,3,3-trimethyl-cyclopent-1-enyl)-ethyl]-urea 
• 72445-68-2 1-(3-Chloro-4-methyl-phenyl)-3-[2-(2,3,3-trimethyl-cyclopent-1-enyl)-ethyl]-urea 

Relevant articles and documents

Copper-catalyzed synthesis of thiazol-2-yl ethers from oxime acetates and xanthates under redox-neutral conditions

A novel copper-catalyzed annulation of oxime acetates and xanthates for the synthesis of thiazol-2-yl ethers with remarkable regioselectivity has been developed. Various oxime acetates, whether derived from aryl ketones or alkyl ketones, or natural product cores are suitable for this conversion. Unique dihydrothiazoles were also obtained when both reaction sites were methine. Mechanistic studies indicated that imino copper(iii) intermediates were involved. In addition, this protocol proceeded under redox-neutral conditions and did not require additives or ligands.

IMPROVED METHOD FOR PRODUCING SPECIFIC OXIMES AND OXIMETHERS

Method for preparing certain oximes and oxime O-methyl ethers by reacting poorly water-soluble carbonyl compounds with salts of hydroxylamine or hydroxylamine O-methyl ether or the free base of hydroxylamine in the presence of certain phosphoric esters or salts thereof of the formula (I) wherein R1, R2 and X are defined as specified in the description.

N-tert-Butyl-N-chlorocyanamide: A new reagent for the efficient preparation of gem-chloronitroso compounds

A new reagent for the efficient preparation of gem-chloronitroso compounds has been developed. The reaction of ketoximes with N-tert-butyl-N- chlorocyanamide takes place instantaneously in carbon tetrachloride at room temperature with excellent yields under mild conditions.