134641-55-7

Basic information

• Product Name: 1,4-diphenyl-5,10-dihydrobenzophthalazine
• Synonyms: 1,4-diphenyl-5,10-dihydrobenzophthalazine
• CAS NO: 134641-55-7
• Molecular Weight: 334.42
• Mol File: 134641-55-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,4-diphenyl-5,10-dihydrobenzophthalazine(CAS DataBase Reference)
• NIST Chemistry Reference: 1,4-diphenyl-5,10-dihydrobenzophthalazine(134641-55-7)
• EPA Substance Registry System: 1,4-diphenyl-5,10-dihydrobenzophthalazine(134641-55-7)

Safety Data

• Hazardous Substances Data: 134641-55-7(Hazardous Substances Data)

Upstream product

• 6830-78-0 3,6-diphenyl-1,2,4,5-tetrazine 
• 612-17-9 1,4-dihydronaphthalene 
• 27714-80-3 9,9-dichloro-1,4-dihydro-4a,8a-methanonaphthalene 
• 39623-22-8 (4aα,8aα)-9,9-dichloro-1,4,5,8-tetrahydro-4a,8a-methanonaphthalene 

Relevant articles and documents

Cycloaddition Reactions of the Methanoannulene Derivative 9,9-Dichloro-1,4-dihydro-4a,8a-methanonaphthalene

9,9-Dichloro-1,4-dihydro-4a,8a-methanonaphthalene (4) adds the electron-deficient dienophiles 4-phenyl-1,2,4-triazoline-3,5-dione, maleic anhydride and dimethyl acetylenedicarboxylate to the α-face to give adducts (5)-(7) respectively; the addition of the alkyne requires Lewis acid catalysis.Inverse electron-demand addition of 3,6-diphenyl-1,2,4,5-tetrazine to the monoene component of (4) in hydrophilic solvent (ethane-1,2-diol) is thwarted; the CCl2 bridge is ejected and the 1,4-dihydronaphthalene formed is captured to give (ultimately) phthalazine (16).Dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate adds to (4) to give the methanobenzophthalazine (17b).