13086-95-8

Basic information

• Product Name: [acetoxy-(2-chlorophenyl)methyl] acetate
• Synonyms: (2-Chlorophenyl)methylene diacetate; methanediol, 1-(2-chlorophenyl)-, diacetate
• CAS NO: 13086-95-8
• Molecular Formula: C₁₁H₁₁ClO₄
• Molecular Weight: 242.6556
• Mol File: 13086-95-8.mol
• Article Data: 64

Chemical Properties

• Boiling Point: 317.379°C at 760 mmHg
• Flash Point: 127.627°C
• Density: 1.268g/cm³
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.519
• CAS DataBase Reference: [acetoxy-(2-chlorophenyl)methyl] acetate(CAS DataBase Reference)
• NIST Chemistry Reference: [acetoxy-(2-chlorophenyl)methyl] acetate(13086-95-8)
• EPA Substance Registry System: [acetoxy-(2-chlorophenyl)methyl] acetate(13086-95-8)

Safety Data

• Hazardous Substances Data: 13086-95-8(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 89-98-5 2-chloro-benzaldehyde 

Downstream Products

• 101884-10-0 bis-(5-chloro-2-hydroxy-phenyl)-(2-chloro-phenyl)-methane 
• 89-98-5 2-chloro-benzaldehyde 
• 119691-04-2 1,2-di(thiophene-2-yl)-2-oxoethyl acetate 
• 51891-93-1 (+/-)-1,2-di(furan-2-yl)-2-oxoethyl acetate 
• 2188-17-2 3,3'-Dimethoxy-benzoinacetat 
• 62398-10-1 2-acetoxy-2-phenylacetophenone 

Relevant articles and documents

An efficient synthesis of diacetates from aldehydes using beta zeolite

A variety of aldehydes react with acetic anhydride in the presence of catalytic amount of β zeolite to afford the corresponding 1,1 diacetates in good to excellent yields.

Catalysis by Solid Superacids; 16. Improved Nafion-H Catalyzed Preparation of 1,1-Diacetates from Aldehydes

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Phospho sulfonic acid as an efficient and recyclable solid acid catalyst for the solvent-free preparation of acylals

Phospho sulfonic acid (PSA) acts as a highly effective and reusable catalyst for the chemo-selective protection of aldehydes with acetic anhydride under solvent-free conditions. The desirable features of this new catalytic methodology include its sustaina

Application of poly(Vinylbenzyltrimethylammonium tribromide) resin as an efficient polymeric catalyst in the acetalization and diacetylation of benzaldehydes

The applications of a new supported tribromide reagent (poly(vinylbenzyltrimethylammonium tribromide) resin) were reported. This supported tribromide resin was used as a catalyst in the acetalization and diacetylation of benzaldehydes under mild conditions with high efficiency. The effects of solvents, and amount of the supported tribromide resin on the reactions were investigated. Under the optimal conditions, most of acetal and 1,1-diacetates of benzaldehydes were selectively obtained in excellent yields.

Chemoselective synthesis of 1,1-diacetates under solvent-free condition using efficient heterogeneous ecofriendly catalyst: P2O5/kaolin

An efficient and chemoselective method for the preparation of acylals from different aldehydes and acetic anhydride using.....kaolin supported catalyst (P2O5). under solvent-free conditions is described herein. The present protocol offers several advantages including use of inexpensive and non-toxic catalyst support i.e., natural kaolin. Preparation of the supported catalyst is easy, the process is simple in operation, maintaining solvent free conditions, with short reaction times, high yields and affording selective protection of aldehyde in presence of ketone.