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129197-02-0

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129197-02-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 129197-02-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,9,1,9 and 7 respectively; the second part has 2 digits, 0 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 129197-02:
(8*1)+(7*2)+(6*9)+(5*1)+(4*9)+(3*7)+(2*0)+(1*2)=140
140 % 10 = 0
So 129197-02-0 is a valid CAS Registry Number.

129197-02-0Downstream Products

129197-02-0Relevant articles and documents

Transition-Metal Free Chemoselective Hydroxylation and Hydroxylation-Deuteration of Heterobenzylic Methylenes

Fu, Yiwei,Li, Hao,Liu, Yonghai,Mang, Zhiguo,Shi, Lei,Sun, Chengyu,Yu, Yang

supporting information, p. 8127 - 8131 (2020/11/03)

We developed an approach for direct selective hydroxylation of heterobenzylic methylenes to secondary alcohols avoiding overoxidation to ketones by using a KOBu-t/DMSO/air system. Most reactions could reach completion in several minutes to give hydroxylated products in 41-76% yields. Using DMSO-d6, this protocol resulted in difunctionalization of heterobenzylic methylenes to afford α-deuterated secondary alcohols (>93% incorporation). By employing this method, active pharmaceutical ingredients carbinoxamine and doxylamine were synthesized in two steps in moderate yields.

Complex-induced proximity effect in the regioselective lithiation of pyridine derivatives

Dhau, Jaspreet S.,Singh, Amritpal,Kasetti, Yoganjaneyulu,Bharatam

, p. 1746 - 1752 (2012/05/04)

The regioselective ring lithiation of BF3-complexed 3-picoline (1a), 3,4-lutidine (1b), and 3,5-lutidine (1c) was studied. The dilithiation of 1a, 1b, and 1c was also investigated to experimentally explore the relative preference of the sites on the substituted pyridine ring for lithiation. The role of the complex-induced proximity effect (CIPE) for inducing lithiation in these moieties was investigated using both experimental and computational studies.

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