121241-52-9

Basic information

• Product Name: {1,2-bis(diphenylphosphino)ethane-P,P'}tris(phenyl isocyanide)iron⁽⁰⁾
• Synonyms: {1,2-bis(diphenylphosphino)ethane-P,P'}tris(phenyl isocyanide)iron⁽⁰⁾
• CAS NO: 121241-52-9
• Molecular Weight: 763.641
• Mol File: 121241-52-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {1,2-bis(diphenylphosphino)ethane-P,P'}tris(phenyl isocyanide)iron⁽⁰⁾(CAS DataBase Reference)
• NIST Chemistry Reference: {1,2-bis(diphenylphosphino)ethane-P,P'}tris(phenyl isocyanide)iron⁽⁰⁾(121241-52-9)
• EPA Substance Registry System: {1,2-bis(diphenylphosphino)ethane-P,P'}tris(phenyl isocyanide)iron⁽⁰⁾(121241-52-9)

Safety Data

• Hazardous Substances Data: 121241-52-9(Hazardous Substances Data)

Upstream product

• 95402-13-4 mer-{FeI(1,2-bis(diphenylphosphino)ethane)(phenyl isocyanide)3}I 

Downstream Products

• 121241-56-3 mer-{FeH(1,2-bis(diphenylphosphino)ethane)(phenyl isocyanide)3}PF₆ 
• 7440-22-4 silver 
• 7440-57-5 gold 
• 10170-69-1 dimanganese decacarbonyl 
• 121257-69-0 {FeBr(1,2-bis(diphenylphosphino)ethane)(phenyl isocyanide)3}⁽¹⁺⁾ 
• 95402-13-4 mer-{FeI(1,2-bis(diphenylphosphino)ethane)(phenyl isocyanide)3}I 
• 121257-70-3 mer-{FeBr(1,2-bis(diphenylphosphino)ethane)(phenyl isocyanide)3}PF₆ 

Relevant articles and documents

Synthesis and Reactivity of Mixed-ligand Isocyanide-Diphosphine Iron(0) Complexes. X-Ray Crystal Structure of cis-(dppe)(CNPh)2(Ph)=C(Me)-C=NPh>>ClO4

Reduction of mer-I with sodium amalgam in tetrahydrofuran gives the very air-sensitive complexes (2a)-(2c) respectively.Compound (2a) reacts with NH4PF6 to give mer-PF6 (3), which is readily transformed to its fac isomer (4) by heating.Reaction of (2a) with SnPh3Cl yields the novel heterodimetallic cation mer-(1+) (5).Addition of CH3I to toluene solutions of complexes (2a)-(2c) gives the neutral compounds I(L-L)(CNR)(R)=C(Me)-C=NR>> (6a)-(6c) respectively which possess a new chelating ligand.Compound (6a) reacts with phenyl isocyanide in the presence of AgClO4 to give cis-(dppe)(CNPh)2(Ph)=C(Me)-C=NPh>>ClO4 (7) and with carbon monoxide in the presence of TlPF6 to give (dppe)(CO)(CNPH)(Ph)=C(Me)-C=NPh>>(1+).For complex (7), a single-crystal X-ray diffraction study was carried out.The iminic nitrogen in (6a) is easily protonated with HClO4 affording the cationic complex I(dppe)(CNPH)(Ph)=C(Me)-C-NHPh>>ClO4.Complex (2a) reacts with allyl bromide to give mainly the undesired mer-(1+) and a small amount of the neutral complex Br(dppe)(CNPh)(Ph)=C(CH2CHCH2)-C=NPh>>.