120915-27-7

Basic information

• Product Name: (Z)-oct-1-ene-1,2-diylbis(phenylsulfane)
• Synonyms: (Z)-oct-1-ene-1,2-diylbis(phenylsulfane)
• CAS NO: 120915-27-7
• Molecular Weight: 328.543
• Mol File: 120915-27-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (Z)-oct-1-ene-1,2-diylbis(phenylsulfane)(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-oct-1-ene-1,2-diylbis(phenylsulfane)(120915-27-7)
• EPA Substance Registry System: (Z)-oct-1-ene-1,2-diylbis(phenylsulfane)(120915-27-7)

Safety Data

• Hazardous Substances Data: 120915-27-7(Hazardous Substances Data)

Upstream product

• 629-05-0 n-octyne 
• 201230-82-2 carbon monoxide 
• 882-33-7 diphenyldisulfane 
• 3186-52-5 O-methyl-S-phenyl thiolcarbonate 
• 66003-76-7 Diphenyliodonium triflate 
• 1666-13-3 diphenyl diselenide 
• 108-98-5 thiophenol 

Relevant articles and documents

Palladium-Catalyzed Regioselective Three-Component Cascade Bisthiolation of Terminal Alkynes

An efficient and novel NHC(N-heterocyclic carbene)-palladium-catalyzed three-component cascade bisthiolation of terminal alkynes, K2S (potassium sulfide) and diaryliodonium salts for the assembly of functionalized (Z)-1,2-bis(arylthio)alkene derivatives has been accomplished for the first time. This unique observation features a broad substrate scope, excellent functional-group tolerance, and high regioselectivity. Especially, an arylthiolate anion from diaryliodonium salts and potassium sulfide was proposed as the key intermediate in the catalytic cycle. (Figure presented.).

Addition of diaryl disulfides to terminal alkynes catalysed by an MCM-41-supported bidentate phosphine palladium(0) complex

A variety of (Z)-1,2-bis(arylthio)-substituted alkenes have been conveniently synthesised in high yields by the stereoselective addition of diaryl disulfides to terminal alkynes catalysed by an MCM-41-supported bidentate phosphine palladium(0) complex. Th

Palladium-catalyzed thioesterirication of alkynes with O-methyl S-phenyl thiocarbonate

-