118220-82-9

Basic information

• Product Name: threo-3-(α-Hydroxybenzyl)-5,5-dimethyl-2-hexanone
• CAS NO: 118220-82-9
• Molecular Weight: 234.338
• Mol File: 118220-82-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: threo-3-(α-Hydroxybenzyl)-5,5-dimethyl-2-hexanone(CAS DataBase Reference)
• NIST Chemistry Reference: threo-3-(α-Hydroxybenzyl)-5,5-dimethyl-2-hexanone(118220-82-9)
• EPA Substance Registry System: threo-3-(α-Hydroxybenzyl)-5,5-dimethyl-2-hexanone(118220-82-9)

Safety Data

• Hazardous Substances Data: 118220-82-9(Hazardous Substances Data)

Upstream product

• 97-94-9 triethyl borane 
• 100-52-7 benzaldehyde 
• 78-94-4 methyl vinyl ketone 
• 558-17-8 tert-Butyl iodide 

Relevant articles and documents

Trialkylborane as an Initiator and Terminator of Free Radical Reactions. Facile Routes to Boron Enolates via α-Carbonyl Radicals and Aldol Reaction of Boron Enolates

A variety of trialkylborane-induced reactions were examined for the preparation of the α-carbonyl radicals: (1) addition of alkyl radical to methyl vinyl ketone, (2) reduction of α-halo ketone, and (3) intramolecular radical addition to α,β-unsaturated carbonyl moiety.Trialkylborane reacted with α-carbonyl radicals to give boron enolates.The resulting boron enolates were efficiently trapped by carbonyl compounds to give β-hydroxy ketones in good yields.