115438-03-4Relevant articles and documents
Selective intermolecular amination of C-H bonds at tertiary carbon centers
Roizen, Jennifer L.,Zalatan, David N.,Du Bois
, p. 11343 - 11346 (2013)
C-H insertion: A method for intermolecular amination of tertiary C-H bonds is described that uses limiting amounts of substrate and a convenient phenol-derived nitrogen source. Structure-selectivity and mechanistic studies suggest that steric interaction between the substrate and active oxidant is the principal determinant of product selectivity. Copyright