1113056-92-0Relevant articles and documents
Diels-Alder reaction of tetraarylcyclopentadienones with benzo[: B] thiophene S, S-dioxides: An unprecedented de-oxygenation vs. sulfur dioxide extrusion
Manikandan, Palani,Karunakaran, Jayachandran,Varathan, Elumalai,Schreckenbach, Georg,Mohanakrishnan, Arasambattu K.
supporting information, p. 15317 - 15320 (2020/12/23)
Diels-Alder reaction of tetraarylcyclopentadienones with benzo[b]thiophene dioxides in xylenes at reflux led to the formation of tetra aryl-substituted dibenzothiophene as well as penta aryl-substituted benzene analogues depending on the influence of aryl substituents present on cyclopentadienones. The intermediate dihydrodibenzothiophene-dioxides underwent aromatization either through de-oxygenation or extrusion of sulfur dioxide to furnish substituted dibenzothiophenes or benzenes. This journal is