106578-68-1Relevant articles and documents
Quinoline formation via a modified Combes reaction: Examination of kinetics, substituent effects, and mechanistic pathways
Sloop, Joseph C.
, p. 110 - 117 (2009)
A comprehensive product regioselectlvity and kinetics study of the modified Combes quinoline synthesis shown below has been undertaken: This is the first reported investigation of the Combes condensation employing 19F NMR spectroscopy to monitor intermedi
Molybdenum(VI) dioxo and oxo-imido complexes of fluorinated β-ketiminato ligands and their use in OAT reactions
Volpe, Manuel,Moesch-Zanetti, Nadia C.
experimental part, p. 1440 - 1449 (2012/03/22)
Substitution of a methyl by a trifluoromethyl moiety in well-known β-ketimines afforded the ligands (Ar)NC(Me)CH2CO(CF3) (HLH, Ar = C6H5; HLMe, A r= 2,6-Me2C6H3/
Extremely narrow-dispersed high molecular weight polyethylene from living polymerization at elevated temperatures with o-F substituted Ti enolatoimines
Yu, Sze-Man,Mecking, Stefan
supporting information; experimental part, p. 13204 - 13205 (2009/02/06)
With a new titanium imineenolato complex, ethylene is polymerized in an unprecedented living fashion affording a polymer with a high molecular weight (Mn > 105 g mol-1) and an extremely narrow distribution (Mw/Mn 1.01) at the same time; the living character is also retained even at an elevated temperature of 75 °C, and blockcopolymers are accessible. Copyright