105187-37-9

Basic information

• Product Name: H(CpCo)4(μ3-CCH3)
• Synonyms: H(CpCo)4(μ3-CCH3)
• CAS NO: 105187-37-9
• Molecular Weight: 524.405
• Mol File: 105187-37-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: H(CpCo)4(μ3-CCH3)(CAS DataBase Reference)
• NIST Chemistry Reference: H(CpCo)4(μ3-CCH3)(105187-37-9)
• EPA Substance Registry System: H(CpCo)4(μ3-CCH3)(105187-37-9)

Safety Data

• Hazardous Substances Data: 105187-37-9(Hazardous Substances Data)

Upstream product

• 767-99-7 2-phenylbut-2-ene 
• 394-46-7 2-fluorostyrene 
• 350-51-6 3-fluorostyrene 

Relevant articles and documents

Organometallic Clusters with Fac-Capping Arene Ligands, 5. - C-H Activation and Formation of a μ3-Arene omplex: Competing Reactions During Assembly of (CpCo)3 Cluster Complexes with Vinylbenzenes as Ligands

A number of ring-substituted styrenes R(C6H4)C2H3 (R=CH3, F) reacts with (1) to give both the cluster complexes 3-η2:η2:η2-(C6H4R)C2H3>> 2-H)(μ3-H)(CpCo)33-1-?:2-?:η2-HCC(C6H4R)>> 2 coordination of the bridging alkyne ligand.In solution the complexes 7 are fluxional and exhibit migration of the alkyne and hydride ligands on the Co3 cluster.Key Words: Cyclopentadienylcobalt / Alkyne cluster / Arene cluster / Bond activation, C-H