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103-17-3

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103-17-3 Usage

Description

Chlorbenside, a generic name for an agricultural toxicant, is an acaricide specifically designed for the control of eggs and larvae of red spider mites. It is characterized by its crystalline form and almond-like odor in its technical grade. Chlorbenside exhibits insolubility in water but is soluble in aromatic hydrocarbons and acetone. It demonstrates resistance to acid and alkaline hydrolysis, making it a suitable choice for agricultural applications.

Uses

Used in Agriculture:
Chlorbenside is used as an acaricide for the control of eggs and larvae of red spider mites. Its effectiveness in managing these pests helps protect crops and maintain agricultural productivity.

Hazard

Skin irritant.

Health Hazard

Low to moderate toxicity in experimentalanimals from oral administration; chroniceffects may produce liver and kidney injuryin humans.LD50 oral (rat): 2000 mg/kg.

Check Digit Verification of cas no

The CAS Registry Mumber 103-17-3 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,0 and 3 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 103-17:
(5*1)+(4*0)+(3*3)+(2*1)+(1*7)=23
23 % 10 = 3
So 103-17-3 is a valid CAS Registry Number.
InChI:InChI=1/C13H10Cl2S/c14-11-3-1-10(2-4-11)9-16-13-7-5-12(15)6-8-13/h1-8H,9H2

103-17-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name chlorbenside

1.2 Other means of identification

Product number -
Other names C 11150000 Chlorbenside

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:103-17-3 SDS

103-17-3Relevant articles and documents

Photocatalytic Deoxygenation of Sulfoxides Using Visible Light: Mechanistic Investigations and Synthetic Applications

Clarke, Aimee K.,Parkin, Alison,Rossi-Ashton, James A.,Taylor, Richard J. K.,Unsworth, William P.

, p. 5814 - 5820 (2020)

The photocatalytic deoxygenation of sulfoxides to generate sulfides facilitated by either Ir[(dF(CF3)ppy)2(dtbbpy)]PF6 or fac-Ir(ppy)3 is reported. Mechanistic studies indicate that a radical chain mechanism operates, which proceeds via a phosphoranyl radical generated from a radical/polar crossover process. Initiation of the radical chain was found to proceed via two opposing photocatalytic quenching mechanisms, offering complementary reactivity. The mild nature of the radical deoxygenation process enables the reduction of a wide range of functionalized sulfoxides, including those containing acid-sensitive groups, in typically high isolated yields.

Synthesis of Air-stable, Odorless Thiophenol Surrogates via Ni-Catalyzed C?S Cross-Coupling

Magné, Valentin,Ball, Liam T.

, p. 8903 - 8910 (2019/06/17)

Thiophenols are versatile synthetic intermediates whose practical appeal is marred by their air sensitivity, toxicity and extreme malodor. Herein we report an efficient catalytic method for the preparation of S-aryl isothiouronium salts, and demonstrate that these air-stable, odorless solids serve as user-friendly sources of thiophenols in synthesis. Diverse isothiouronium salts featuring synthetically useful functionality are readily accessible by nickel-catalyzed C?S cross-coupling of (hetero)aryl iodides and thiourea. Convenient, chromatography-free isolation of these salts is achieved by precipitation, allowing the methodology to be applied directly to large scales. Thiophenols are liberated from the corresponding isothiouronium salts upon treatment with a weak base, enabling an in situ release/S-functionalization strategy that entirely negates the need to isolate, purify or manipulate these noxious reagents.

Synthesis of thioethers via metal-free reductive coupling of tosylhydrazones with thiols

Ding, Qiuping,Cao, Banpeng,Yuan, Jianjun,Liu, Xianjin,Peng, Yiyuan

supporting information; experimental part, p. 748 - 751 (2011/03/22)

A metal-free procedure for the synthesis of thioethers is described via the base-promoted reductive coupling of tosylhydrazones with thiols through an insertion of a carbene into the S-H bond.

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