102687-65-0

Basic information

• Product Name: trans-1-Chloro-3,3,3-trifluoroprop-1-ene
• Synonyms: (1E)-1-Chloro-3,3,3-trifluoroprop-1-ene;trans-1-Chloro-3,3,3-trifluoroprop-1-ene
• CAS NO: 102687-65-0
• Molecular Formula: C₃H₂ClF₃
• Molecular Weight: 130.4961896
• Mol File: 102687-65-0.mol
• Article Data: 58

Chemical Properties

• Boiling Point: 20.8 °C
• Appearance: /
• Density: 1.312±0.06 g/cm3(Predicted)
• Vapor Pressure: 106.5kPa at 19.93℃
• CAS DataBase Reference: trans-1-Chloro-3,3,3-trifluoroprop-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: trans-1-Chloro-3,3,3-trifluoroprop-1-ene(102687-65-0)
• EPA Substance Registry System: trans-1-Chloro-3,3,3-trifluoroprop-1-ene(102687-65-0)

Safety Data

• Hazardous Substances Data: 102687-65-0(Hazardous Substances Data)

Usage

Description

Trans-1-Chloro-3,3,3-trifluoroprop-1-ene is a specialized complex chemical compound that belongs to the class of halogenated alkenes. It is characterized by the presence of chlorine and fluorine atoms, with one of the carbon atoms in the carbon-carbon double bond carrying a halogen atom. trans-1-Chloro-3,3,3-trifluoroprop-1-ene is less commonly found and is mostly used in the field of advanced chemistry for various types of research and experiments. Due to its potential reactivity and the presence of chlorine and fluorine, it should be handled with care under controlled measures. The physical, chemical, and toxicity properties of trans-1-Chloro-3,3,3-trifluoroprop-1-ene are still being explored, and further research is required to fully understand its potential applications and safety considerations.

Uses

Used in Advanced Chemistry Research:
Trans-1-Chloro-3,3,3-trifluoroprop-1-ene is used as a research compound in the field of advanced chemistry for various types of experiments and studies. Its unique structure and reactivity as a halogenated alkene make it a valuable subject for investigation.
Used in Chemical Synthesis:
Due to its reactivity and the presence of chlorine and fluorine atoms, trans-1-Chloro-3,3,3-trifluoroprop-1-ene can be used as a building block or intermediate in the synthesis of more complex organic compounds. Its potential applications in chemical synthesis are still being explored, and further research is needed to fully understand its capabilities and limitations.
Used in Material Science:
The unique properties of trans-1-Chloro-3,3,3-trifluoroprop-1-ene, such as its reactivity and the presence of halogen atoms, may make it suitable for the development of new materials with specific characteristics. Its potential applications in material science are still under investigation, and more research is required to determine its suitability and performance in various applications.
Used in Pharmaceutical Development:
Although the toxicity properties of trans-1-Chloro-3,3,3-trifluoroprop-1-ene are still being explored, its unique structure and reactivity may offer potential applications in the development of new pharmaceutical compounds. Further research is needed to assess its safety, efficacy, and potential therapeutic applications.

Upstream product

• 23153-23-3 1,1,1,3,3-pentachloropropane 
• 149329-29-3 1-chloro-1,3,3,3-tetrafluoropropane 
• 460-69-5 1,1-dichloro-3,3,3-trifluoropropane 
• 18611-43-3 1,1,3,3-tetrachloro-1-propene 
• 29118-24-9 trans-1,3,3,3-tetrafluoropropene 
• 29118-25-0 (Z)-1,3,3,3-tetrafluoropropene 
• 21700-31-2 1,1,1,2,3-pentachloro-propane 
• 431-31-2 1,1,1,2,3-pentafluoropropane 
• 460-73-1 1,1,1,3,3-Pentafluoropropane 
• 99728-16-2 (Z)-1-chloro-3,3,3-trifluoro-1-propene 
• 1645-83-6 1,3,3,3-tetrafluoro-propene 
• 460-63-9 1,1,3-trichloro-3,3-difluoropropane 
• 2730-43-0 1-chloro-3,3,3-trifluoropropene 
• 661-54-1 3,3,3-trifluoroprop-1-yne 

Downstream Products

• 460-73-1 1,1,1,3,3-Pentafluoropropane 
• 29118-24-9 trans-1,3,3,3-tetrafluoropropene 
• 29118-25-0 (Z)-1,3,3,3-tetrafluoropropene 
• 460-40-2 3,3,3-trifluoropropanal 
• 99728-16-2 (Z)-1-chloro-3,3,3-trifluoro-1-propene 
• 949112-29-2 (E)-4-chloro-6,6,6-trifluoro-1-phenylhex-4-en-3-ol 
• 94792-93-5 6,6,6-Trifluoro-1-phenyl-4-hexyn-3-ol 
• 949112-37-2 [(E)-1-chloro-3,3,3-trifluoroprop-1-en-1-yl]cyclohexanol 
• 96302-93-1 1-(3,3,3-trifluoro-1-propynyl)-1-cyclohexanol 
• 928658-43-9 1-(4'-methylphenyl)-4,4,4-trifluorobut-2-yn-1-ol 
• 949112-30-5 (E)-2-chloro-4,4,4-trifluoro-1-(4-methylphenyl)but-2-en-1-ol 
• 949112-34-9 (E)-2-chloro-4,4,4-trifluoro-1-(4-nitrophenyl)but-2-en-1-ol 
• 1184844-17-4 4,4,4-trifluoro-1-(4-nitrophenyl)but-2-yn-1-ol 
• 949112-27-0 (E)-2-chloro-4,4,4-trifluoro-1-phenylbut-2-en-1-ol 

Relevant articles and documents

Stereoselective synthesis of cis-1-chloro-3,3,3-trifluoropropene

Stereoselective synthesis of cis-1233zd by the reaction of 3,3,3-trifluoropropyne and HCl over the catalysts of copper(I) chloride on activated carbon was discovered.

Preparation method of E-1-halogen-3, 3, 3-trifluoropropene

The invention discloses a preparation method of E-1-halogen-3, 3, 3-trifluoropropene. The preparation method comprises the following steps: in the presence of a block catalyst, carrying out gas-phase fluorination reaction on 1, 1, 1, 3, 3-pentachloropropane and hydrogen fluoride in a tubular reactor to obtain a main product E-1-chlorine-3, 3, 3-trifluoropropene and a small amount of product Z-1-chlorine-3, 3, 3-trifluoropropene; furthermore, in the presence of the block catalyst, E-1-chlorine-3, 3, 3-trifluoropropene or/and Z-1-chlorine-3, 3, 3-trifluoropropene and hydrogen fluoride are subjected to a gas-phase fluorination reaction in the tubular reactor, and a main product E-1, 3, 3, 3-tetrafluoropropene is obtained. The one-way yield of the method is high; especially for the second-step process, only HCl in the product flow in the first step needs to be removed, and the remaining substances can be directly used for fluorination reaction after new HF is added. The block catalyst has the characteristics of high activity and long service life.

Method for preparing 3, 3, 3-trifluoropropyne through gas-phase dehydrohalogenation

The invention discloses a method for preparing 3, 3, 3-trifluoropropyne through gas-phase dehydrohalogenation. The method comprises the following steps: taking 1-halogen-3, 3, 3-trifluoropropene or/and 2-halogen-3, 3, 3-trifluoropropene (halogen = F or Cl or Br or I) as a raw material, and carrying out gas-phase dehydrohalogenation reaction in the presence of a catalyst to obtain the 3, 3, 3-trifluoropropyne. The method disclosed by the invention is mainly used for producing the 3, 3, 3-trifluoropropyne in a gas-phase continuous circulation manner at a high conversion rate and high selectivity.

PROCESS FOR THE PRODUCTION OF TRANS-1-CHLORO-3,3,3-TRIFLUOROPROPENE

A process for the production of trans-1-chloro-3,3,3-trifluoropropene comprises the steps of: i) providing a reactor comprising a cover, a bottom, sidewalls connecting said bottom and said cover, at least one reagent supply line and at least one line for drawing off the products formed, said reactor further containing a liquid phase A; ii) providing a stream B comprising hydrofluoric acid heated to a temperature T1 of from 100° C. to 170° C. and providing a stream C comprising 1,1,3,3-tetrachloropropene and/or 1,3,3,3-tetrachloropropene; stream B and stream C supplying said reactor via said at least one reagent supply line; iii) reacting, in liquid phase A, stream B with stream C to form a stream D comprising trans-1-chloro-3,3,3-trifluoropropene. Step iii) is carried out at a temperature T2 of between 50° C. and 110° C., and the temperature difference between temperature T1 and temperature T2 is greater than 30° C.