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Basic Information
CAS No.: 421-20-5
Name: METHYL FLUOROSULFONATE
Article Data: 26
Molecular Structure:
Molecular Structure of 421-20-5 (METHYL FLUOROSULFONATE)
Formula: CH3 F O3 S
Molecular Weight: 114.097
Synonyms: Fluorosulfuricacid, methyl ester (8CI,9CI); Methyl fluorosulfate (7CI); Methyl fluosulfonate(6CI); Magic Methyl; Methyl fluorosulfonate
Density: 1.464g/cm3
Melting Point: -95°
Boiling Point: 93°Cat760mmHg
Flash Point: 10°C
Hazard Symbols: Toxic. Strong irritant to tissue, inhalation of fume must be avoided. Reacts with water, steam, and acids, evolving corrosive vapor.
Risk Codes: 34
Safety: Poison by inhalation and ingestion. Moderately toxic by skin contact. A skin, mucous membrane, and severe eye irritant. Mutation data reported. Reacts with water, steam, or acids to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of F and SOx.
PSA: 51.75000
LogP: 0.92790
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Chemistry

The IUPAC name of Methyl fluorosulfate (CAS NO.421-20-5): Fluorosulfonyloxymethane
Synonyms: Fluorosulfuricacid,methylester ; Fluorosulfuricacidmethylester ; Magicmethyl ; Methylfluorosulfate ; Methylfluosulfonate ; Fluorosulfonic acid methyl ester ; Methyl fluorosulfonate ; Methyl fluorosulphonate
CAS: 421-20-5 
EINECS: 207-004-3 
Molecular Formula: CH3FO3S
Formula Weight: 114.1 g/mol
Molecular Structure:

Index of Refraction: 1.363 
Density: 1.464 g/cm
Flash Point: 10 °C 
Boiling Point: 93 °C at 760 mmHg

Toxicity Data With Reference

The toxicity of Methyl fluorosulfate (CAS NO.421-20-5): 

1.    

eye-rbt 100 mg/4 sec rns SEV

    AIHAAP    American Industrial Hygiene Association Journal. 40 (1979),600.
2.    

mmo-sat 4 µg/plate

    MUREAV    Mutation Research. 51 (1978),285.
3.    

ihl-rat LC50:5 ppm/1H

    AIHAAP    American Industrial Hygiene Association Journal. 40 (1979),600.
4.    

orl-mus LD50:112 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 40 (1979),600.
5.    

skn-rbt LDLo:455 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 40 (1979),600.

Safety Profile

The Hazard Codes of Methyl fluorosulfate (CAS NO.421-20-5): CorrosiveC
Risk Statements:R34:Causes burns.
Safety Statements:S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 

Poison by inhalation and ingestion. Moderately toxic by skin contact. A skin, mucous membrane, and severe eye irritant. Mutation data reported. Reacts with water, steam, or acids to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of F and SOx.