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CAS No.: | 22737-37-7 |
---|---|
Name: | N,O-BIS(TRIMETHYLSILYL)HYDROXYLAMINE |
Article Data: | 9 |
Molecular Structure: | |
Formula: | C6H19NOSi2 |
Molecular Weight: | 177.394 |
Synonyms: | Silylamine,1,1,1-trimethyl-N-(trimethylsiloxy)- (8CI);1,1,1-Trimethyl-N-(trimethylsiloxy)silylamine;N,O-Bis(trimethylsilyl)hydroxylamine; |
EINECS: | 245-188-7 |
Density: | 0.828 g/cm3 |
Boiling Point: | 139.8 °C at 760 mmHg |
Flash Point: | 38.3 °C |
Appearance: | Clear colorless liquid |
Hazard Symbols: | Xi |
Risk Codes: | 10-36/37/38-34 |
Safety: | 26-45-36/37/39 |
Transport Information: | UN 1993 |
PSA: | 21.26000 |
LogP: | 2.56830 |
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The Silanamine,1,1,1-trimethyl-N-[(trimethylsilyl)oxy]-, with CAS registry number 22737-37-7, belongs to the following product categories: (1)Hydroxylamines; (2)Hydroxylamines (N-Substituted); (3)Hydroxylamines (O-Substituted); (4)Si (Classes of Silicon Compounds); (5)Si-N Compounds; (6)Trimethylsilylazide, etc.; (7)Nitrogen Compounds; (8)Organic Building Blocks. It has the systematic name of 1,1,1-trimethyl-N-[(trimethylsilyl)oxy]silanamine. This chemical is a kind pf clear colorless liquid. And it should be stored at the temperature of 2-8°C. And the chemical formula of this chemical is C6H19NOSi2. What's more, its EINECS is 245-188-7.
Physical properties of Silanamine,1,1,1-trimethyl-N-[(trimethylsilyl)oxy]-: (1)ACD/LogP: 2.77; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.2; (4)ACD/LogD (pH 7.4): 2.76; (5)ACD/BCF (pH 5.5): 20.21; (6)ACD/BCF (pH 7.4): 72.98; (7)ACD/KOC (pH 5.5): 205.78; (8)ACD/KOC (pH 7.4): 743.21; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 3; (12)Polar Surface Area: 12.47 Å2; (13)Index of Refraction: 1.405; (14)Molar Refractivity: 52.62 cm3; (15)Molar Volume: 214.2 cm3; (16)Polarizability: 20.86×10-24cm3; (17)Surface Tension: 17.2 dyne/cm; (18)Density: 0.828 g/cm3; (19)Flash Point: 38.3 °C; (20)Enthalpy of Vaporization: 37.7 kJ/mol; (21)Boiling Point: 139.8 °C at 760 mmHg; (22)Vapour Pressure: 6.33 mmHg at 25°C.
Preparation: this chemical can be prepared by chloro-trimethyl-silane. This reaction will need reagent NH2OH and solvent tetrahydrofuran.
When you are using this chemical, please be cautious about it as the following:
The Silanamine,1,1,1-trimethyl-N-[(trimethylsilyl)oxy]- irritates to eyes, respiratory system and skin. And this chemical is flammable, and it may cause burns, so keep it away from sources of ignition. When use it, wear suitable protective clothing, gloves and eye/face protection. If contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
You can still convert the following datas into molecular structure:
(1)SMILES: O(N[Si](C)(C)C)[Si](C)(C)C
(2)InChI: InChI=1/C6H19NOSi2/c1-9(2,3)7-8-10(4,5)6/h7H,1-6H3
(3)InChIKey: ZAEUMMRLGAMWKE-UHFFFAOYAY
(4)Std. InChI: InChI=1S/C6H19NOSi2/c1-9(2,3)7-8-10(4,5)6/h7H,1-6H3
(5)Std. InChIKey: ZAEUMMRLGAMWKE-UHFFFAOYSA-N