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Basic Information
CAS No.: 109-82-0
Name: Methylenaminoacetonitrile
Article Data: 17
Molecular Structure:
Molecular Structure of 109-82-0 (Methylenaminoacetonitrile)
Formula: C3H4N2
Molecular Weight: 68.0782
Synonyms: Acetonitrile,(methyleneamino)- (8CI,9CI);Glycinonitrile, N-methylene- (6CI,7CI);MAAN;N-methylene-glycinonitrile;NSC 128385;NSC 3486;NSC 57883;
EINECS: 203-709-5
Density: 0.84 g/cm3
Melting Point: 127-130 °C
Boiling Point: 151.2 °C at 760 mmHg
Flash Point: 45.2 °C
Appearance: White crystals
Hazard Symbols: HarmfulXn
Risk Codes: 36/37/38-20/21/22
Safety: 36/37/39-26-22
PSA: 36.15000
LogP: 0.21058
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Chemistry

Chemical Name: Methylenaminoacetonitrile
IUPAC NAME: 2-(Methylideneamino)acetonitrile
CAS No.: 109-82-0
EINECS: 203-709-5
RTECS: MC1925000
Molecular Formula: C3H4N2
Molecular Weight: 68.08 g/mol
Melting Point: 127-130 °C
Density: 0.84 g/cm3 
Flash Point: 45.2 °C
Boiling Point: 151.2 °C at 760 mmHg
Following is the structure of α-Hydroformamine cyanide (109-82-0):


The chemical synonymous of α-Hydroformamine cyanide (109-82-0) are (Methyleneamino)-acetonitril ; Glycinonitrile, n-methylene- ; -Hydroformaminecyanide ; Maan ; Methyleniminoacetonitrile ; N-methylene-glycinonitril ; Usafdo-5 ; N-methylenaminoacetonitrile

Uses

 α-Hydroformamine cyanide (109-82-0) is mainly used as an intermediate for organic synthesis.

Toxicity Data With Reference

1.    

ipr-mus LD50:200 mg/kg

    NTIS**    National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 .
2.    

par-mus LDLo:2000 mg/kg

    CBCCT*    “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 7 (1955),689.

Consensus Reports

Reported in EPA TSCA Inventory. Cyanide and its compounds are on The Community Right-To-Know List.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by parenteral route. When heated to decomposition it emits toxic fumes of NOx and CN. See also NITRILES.
Hazard Codes:
Xn: Harmful
Risk Statements about α-Hydroformamine cyanide (109-82-0):
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38 Irritating to eyes, respiratory system and skin. 
Safety Statements about α-Hydroformamine cyanide (109-82-0):
S22 Do not breathe dust. 
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. 
Attention:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.