(2-Furylmethoxy)trimethylsilane

Base Information

• Chemical Name: (2-Furylmethoxy)trimethylsilane
• CAS No.: 2846-62-0
• Molecular Formula: C8H14O2Si
• Molecular Weight: 170.283
• Hs Code.: 2932190090
• Mol file: 2846-62-0.mol

Synonyms:(furan-2-ylmethoxy)trimethylsilane;furan-2-ylmethyl trimethylsilyl ether;trimethyl(furan-2-yl-methoxy)silane;furfuryloxy-trimethyl-silane;

Chemical Property of (2-Furylmethoxy)trimethylsilane

Chemical Property:

• PSA: 22.37000
• LogP: 2.63110

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2-Furylmethoxy)trimethylsilane

There total 5 articles about (2-Furylmethoxy)trimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → (furan-2-ylmethoxy)trimethylsilane (2846-62-0)

Guidance literature:

With phenyltrimethylammonium tribromide; In dichloromethane; at 20 ℃; for 0.166667h; chemoselective reaction;

DOI:10.1016/S1872-2067(10)60107-6

Reference yield: 98.0%

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + chloro-trimethyl-silane (75-77-4) → (furan-2-ylmethoxy)trimethylsilane (2846-62-0)

Guidance literature:

With iron perchlorate hexahydrate; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1080/10426500802336606

Reference yield: 82.0%

(2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + Bis(trimethylsilyl)ethyne (14630-40-1) → (furan-2-ylmethoxy)trimethylsilane (2846-62-0)

Guidance literature:

With potassium hexamethylsilazane; In neat (no solvent); at 40 ℃; for 1h; Inert atmosphere; Green chemistry;

DOI:10.1002/ejoc.202000573

upstream raw materials:

(2-furyl)methyl alcohol

chloro-trimethyl-silane

1-(Trimethylsilyl)imidazole

1,1,1,3,3,3-hexamethyl-disilazane

Downstream raw materials:

(2-furyl)methyl alcohol

furfurylacetate

Refernces

• 1、 Oladee, Razieh,Zareyee, Daryoush,Khalilzadeh, Mohammad A.. "KF/clinoptilolite NPs: An efficient and heterogeneous catalyst for chemoselective silylation of alcohols and phenols". . p. 731 - 737. Retrieved 2021/03/31.
• 2、 Anbu, Nagaraj,Vijayan, Chellappa,Dhakshinamoorthy, Amarajothi. "A simple and efficient room temperature silylation of diverse functional groups with hexamethyldisilazane using CeO2 nanoparticles as solid catalysts". . . Retrieved 2019/06/08.