11-Bromoundecanamide

Base Information

• Chemical Name: 11-Bromoundecanamide
• CAS No.: 5875-26-3
• Molecular Formula: C₁₁H₂₂BrNO
• Molecular Weight: 264.206
• Hs Code.: 2924199090
• European Community (EC) Number: 806-324-6
• NSC Number: 403235
• DSSTox Substance ID: DTXSID60323166
• Nikkaji Number: J2.353.419C
• Wikidata: Q82082021
• Mol file: 5875-26-3.mol

Synonyms:11-Bromoundecanamide;5875-26-3;Undecanamide, 11-bromo-;NSC403235;11-Bromoundecaneamide;11-Bromoundecanamide #;11-Bromoundecanamide 97;11-Bromoundecanamide, 97%;SCHEMBL5573307;DTXSID60323166;AKOS015913278;NSC 403235;NSC-403235

Chemical Property of 11-Bromoundecanamide

Chemical Property:

• Vapor Pressure: 4.37E-06mmHg at 25°C
• Melting Point: 88-92 °C (lit.)
• Refractive Index: 1.485
• Boiling Point: 383.5 °C at 760 mmHg
• PKA: 16.61±0.40(Predicted)
• Flash Point: 185.7 °C
• PSA: 43.09000
• Density: 1.178 g/cm³
• LogP: 4.07780
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 10
• Exact Mass: 263.08848
• Heavy Atom Count: 14
• Complexity: 139

Purity/Quality:

98%,99%, ^*data from raw suppliers

11-Bromoundecanamide 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(CCCCCBr)CCCCC(=O)N

Technology Process of 11-Bromoundecanamide

There total 3 articles about 11-Bromoundecanamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

11-bromoundecanoic acid (2834-05-1) → 11-bromoundecanamide (5875-26-3)

Guidance literature:

With ammonium hydroxide; chloroformic acid ethyl ester; triethylamine; Yield given. Multistep reaction; 1) acetone, -15 - -10 deg C, 90 min; 60 min;

DOI:10.1002/hlca.19830660741

Reference yield:

11-bromoundecanoyl chloride (15949-84-5) → 11-bromoundecanamide (5875-26-3)

Guidance literature:

With ammonia; at 0 ℃;

Reference yield:

C14H25BrO4 → 11-bromoundecanamide (5875-26-3)

Guidance literature:

With ammonium hydroxide; In acetone; for 2h; Yield given;

DOI:10.1002/hlca.19830660741

upstream raw materials:

11-bromoundecanoyl chloride

11-bromoundecanoic acid

Downstream raw materials:

11-bromoundecanenitrile

11-mercaptoundecaneamide

undec-10-enamide

Refernces

• 1、 Thuo, Martin M.,Reus, William F.,Simeone, Felice C.,Kim, Choongik,Schulz, Michael D.,Yoon, Hyo Jae,Whitesides, George M.. "Replacing -CH2CH2- with -CONH- does not significantly change rates of charge transport through AgTS-SAM//Ga 2O3/EGaIn junctions". supporting information; experimental part. p. 10876 - 10884. Retrieved 2012/08/28.
• 2、 Voss, Gundula,Gerlach, Hans. "Orthocarbonsaeure-ester mit 2,4,10-Trioxaadamantanstruktur als Carboxylschutzgruppe; Verwendung zur Synthese von substituierten Carbonsaeuren mit Hilfe von Grignard-Reagenzien". . p. 2294 - 2307. Retrieved 2007/10/02.