Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine)

Base Information

• Chemical Name: Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine)
• CAS No.: 1082604-16-7
• Molecular Formula: C₁₀H₉N₃*C₁₄H₈O₅*Cu
• Molecular Weight: 490.962
• Mol file: 1082604-16-7.mol

Synonyms:

Chemical Property of Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine)

There total 2 articles about Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

di(pyridin-2-yl)amine (1202-34-2) + copper(II) nitrate hexahydrate + oxybis(benzoic acid) (2215-89-6) → Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine) (1082604-16-7)

Guidance literature:

With triethylamine; In water; High Pressure; stirring a mixt. of Cu salt, acid, pyridine deriv. and amine in water for 20 min in air, heating to 140°C for 5 d, cooling to room temp. at 5°C/h; elem. anal.;

DOI:10.1016/j.molstruc.2007.12.032

Reference yield: 55.0%

di(pyridin-2-yl)amine (1202-34-2) + copper(II) sulfate heptahydrate + oxybis(benzoic acid) (2215-89-6) → Cu(II)(1,2-bis(4-pyridyl)ethene)(dipyridin-2-ylamine) (1082604-16-7)

Guidance literature:

With NaOH; In water; High Pressure; mixt. of CuSO4*6H2O, 4,4'-oxy-bis(benzoic acid), dipyridin-2-ylamine (1:1:1) and NaOH stirred in H2O for 20 min (air), heated in an autoclave at150°C for 48 h; slowly cooled to room temp., elem. anal.;

DOI:10.1002/ejic.200800898

upstream raw materials:

di(pyridin-2-yl)amine

oxybis(benzoic acid)

Refernces

• 1、 Tang, Long,Li, Dongsheng,Fu, Feng,Wu, Yapan,Wang, Yaoyu,Hu, Huaiming,Wang, Enbo. "The structure and magnetic properties of a 3D pillared-layer polymer and two helical chains constructed from flexible ligands". . p. 344 - 353. Retrieved 2009/02/06.