PdCl(P(OC₆H₅)3)(P(OC₆H₅)2OC₆H₄)

Base Information

• Chemical Name: PdCl(P(OC₆H₅)3)(P(OC₆H₅)2OC₆H₄)
• CAS No.: 41871-86-7
• Molecular Formula: C₃₆H₂₉ClO₆P₂Pd
• Molecular Weight: 761.443
• Mol file: 41871-86-7.mol

Synonyms:

Chemical Property of PdCl(P(OC₆H₅)3)(P(OC₆H₅)2OC₆H₄)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of PdCl(P(OC₆H₅)3)(P(OC₆H₅)2OC₆H₄)

There total 1 articles about PdCl(P(OC₆H₅)3)(P(OC₆H₅)2OC₆H₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

triphenyl phosphite (101-02-0) + [Pd(μ-C1)(P(OPh)2)(OC6H4)]2 → PdCl(P(OC6H5)3)(P(OC6H5)2OC6H4) (41871-86-7)

Guidance literature:

In dichloromethane; stirring (10 min); evapn. (vac.), crystn. (CH2Cl2/pentane); elem. anal.;

Reference yield:

PdCl(P(OC6H5)3)(P(OC6H5)2OC6H4) (41871-86-7) + K{Fe{Si(OMe)3}(CO)3(η1-dppm) (123674-03-3) → {Fe(Si(OCH3)3)(CO)3(((C6H5)2P)2CH2)Pd(P(OC6H5)2(OC6H4))}

Guidance literature:

In tetrahydrofuran; addn. of a soln. of the Fe-complex to a stirred suspn. of the Pd-complex in THF at -30°C, sirred for 1 h, react. under N2; removal of the solvent in vac. at -20°C, warm to room temp., filtn., addn. of pentane, filtn., dried in vac., recrystn. from THF-pentane;

DOI:10.1016/0022-328X(93)83368-6

upstream raw materials:

triphenyl phosphite

Refernces