9-Acetyl-3,6-diiodocarbazole

Base Information

• Chemical Name: 9-Acetyl-3,6-diiodocarbazole
• CAS No.: 606129-89-9
• Molecular Formula: C14H9I2NO
• Molecular Weight: 461.0363
• Hs Code.: 2933990090
• DSSTox Substance ID: DTXSID20539807
• Wikidata: Q82415613
• Mol file: 606129-89-9.mol

Synonyms:9-Acetyl-3,6-diiodocarbazole;606129-89-9;1-(3,6-Diiodo-9H-carbazol-9-yl)ethanone;1-(3,6-DIIODOCARBAZOL-9-YL)ETHANONE;MFCD10000947;1-(3,6-DIIODO-9H-CARBAZOL-9-YL)ETHAN-1-ONE;C14H9I2NO;SCHEMBL872231;DTXSID20539807;AKOS015837724;CS-W014445;AC-27850;AS-64032;SY054447;A2051;T71118;A868926

Chemical Property of 9-Acetyl-3,6-diiodocarbazole

Chemical Property:

• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 228 °C
• Refractive Index: 1.771
• Boiling Point: 453.808 °C at 760 mmHg
• Flash Point: 228.255 °C
• PSA: 22.00000
• Density: 2.145 g/cm³
• LogP: 4.66380
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Solubility.: soluble in Tetrahydrofuran
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 460.87736
• Heavy Atom Count: 18
• Complexity: 323

Purity/Quality:

98%,99%, ^*data from raw suppliers

9-Acetyl-3,6-diiodocarbazole ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)N1C2=C(C=C(C=C2)I)C3=C1C=CC(=C3)I

Technology Process of 9-Acetyl-3,6-diiodocarbazole

There total 5 articles about 9-Acetyl-3,6-diiodocarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3,6-diiodocarbazole (57103-02-3) + acetic anhydride (108-24-7) → 9-acetyl-3,6-diiodo carbazole (606129-89-9)

Guidance literature:

With boron complex; for 0.166667h; Reflux;

Reference yield:

9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-acetyl-3,6-diiodo carbazole (606129-89-9)

Guidance literature:

Multi-step reaction with 2 steps

1: glacial acetic acid; potassium iodide; potassium iodate

2: concentrated sulfuric acid

With potassium iodate; sulfuric acid; acetic acid; potassium iodide;

Reference yield:

9H-carbazole (86-74-8,105184-46-1,97960-57-1) → 9-acetyl-3,6-diiodo carbazole (606129-89-9)

Guidance literature:

Multi-step reaction with 2 steps

1: KI; KIO₃ / acetic acid

2: BF₃Et₂O

With potassium iodate; boron trifluoride diethyl etherate; potassium iodide; In acetic acid;

DOI:10.1246/cl.2003.674

upstream raw materials:

3,6-diiodocarbazole

acetic anhydride

9H-carbazole

diphenylamine

Downstream raw materials:

3,6-bis(triphenylsilyl)carbazole

9-acetyl-3,6-bis(triphenylsilyl)carbazole

Refernces

• 1、 Guo, Wang,Wang, Xuepu,Zhou, Bei,Zhang, Kaka. "Achieving Purely-Organic Room-Temperature Aqueous Phosphorescence via a Two-Component Macromolecular Self-Assembly Strategy". . p. 3469 - 3474. Retrieved 2020/10/02.
• 2、 Yu, Lin-Feng,Ge, Cong-Wu,Wang, Jin-Tu,Xiang, Xuan,Li, Wei-Shi. "Modification of a donor-acceptor photovoltaic polymer by integration of optoelectronic moieties into its side chains". . p. 57 - 66. Retrieved 2015/01/30.