BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE

Base Information

• Chemical Name: BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE
• CAS No.: 149391-23-1
• Molecular Formula: C₁₂H₂₄Cl₄S₂Ti
• Molecular Weight: 422.147
• Mol file: 149391-23-1.mol

Synonyms:Tetrachlorobis(cyclohexylmercapto)titanium

Chemical Property of BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE

Chemical Property:

• Melting Point: 78°C
• Refractive Index: ">
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 77.60000
• Density: g/cm³
• LogP: 7.25580
• Sensitive.: Moisture Sensitive

Purity/Quality:

98%min ^*data from raw suppliers

Bis(mercaptocyclohexane)titanium tetrachloride, 99.9% (metals basis) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE

There total 2 articles about BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Cyclohexanethiol (1569-69-3) + titanium tetrachloride (7550-45-0) → TiCl4(HSC6H11)2 (149391-23-1)

Guidance literature:

In dichloromethane; inert atmosphere; stirring (room temp., 2 h); evapn., extg. (hexane), filtering, crystn. (-20°C), drying (vac.); elem. anal.;

DOI:10.1016/s0277-5387(97)00309-4

Reference yield: 77.0%

Cyclohexanethiol (1569-69-3) + titanium tetrachloride (7550-45-0) → {TiCl4(C6H11SH)2} (149391-23-1)

Guidance literature:

In hexane; 2 equivalents of cyclohexanethiol at ambient temperature;; solvent evaporation; elem. anal.;;

upstream raw materials:

Cyclohexanethiol

titanium tetrachloride

Refernces

• 1、 Winter, Charles H.,Lewkebandara, T. Suren,Proscia, James W.,Rheingold, Arnold L.. "A class of single-source precursors to titanium disulfide films. Synthesis, structure, and chemical vapor deposition studies of [TiCl4(HSR)2]". . p. 3807 - 3808. Retrieved 2008/10/08.