5,10-DIHYDRO-PHENAZINE

Base Information

• Chemical Name: 5,10-DIHYDRO-PHENAZINE
• CAS No.: 613-32-1
• Molecular Formula: C12H10N2
• Molecular Weight: 182.225
• Hs Code.: 29339900
• Mol file: 613-32-1.mol

Synonyms:5,10-Dihydrophenazine;Dihydrophenazine;N,N'-Dihydrophenazine;NSC 402913;

Chemical Property of 5,10-DIHYDRO-PHENAZINE

Chemical Property:

• Vapor Pressure: 2.54E-05mmHg at 25°C
• Melting Point: 315-316 °C
• Refractive Index: 1.624
• Boiling Point: 358.5 °C at 760 mmHg
• PKA: 6.42±0.20(Predicted)
• Flash Point: 236.2 °C
• PSA: 31.58000
• Density: 1.152 g/cm³
• LogP: 3.21140
• Storage Temp.: Keep in dark place,Inert atmosphere,Store in freezer, under -20°C

Purity/Quality:

97% ^*data from raw suppliers

5,10-Dihydrophenazine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5,10-DIHYDRO-PHENAZINE

There total 24 articles about 5,10-DIHYDRO-PHENAZINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Phenazin (92-82-0) → 5,10-dihydrophenazine (613-32-1)

Guidance literature:

With sodium dithionite; water; In ethanol; for 2.5h; Ambient temperature;

Reference yield: 72.1%

2-iodophenylamine (615-43-0) → 5,10-dihydrophenazine (613-32-1)

Guidance literature:

With 18-crown-6 ether; copper; caesium carbonate; In 1,2-dichloro-benzene; for 24h; Reflux;

Reference yield: 70.0%

2-bromoaniline (615-36-1) → 5,10-dihydrophenazine (613-32-1)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; acetophenone p-toluenesulfonylhydrazone; lithium tert-butoxide; In 1,4-dioxane; at 100 ℃; for 6h; Inert atmosphere;

DOI:10.1021/jo301987c

upstream raw materials:

Phenazin

bis(2-nitrophenyl)amine

benzene-1,2-diol

1,2-diamino-benzene

Downstream raw materials:

phenazine; compound with 5,10-dihydro-phenazine

phenazine; compound with 5,10-dihydro-phenazine

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester

1-bromophenazine

Refernces

• 1、 Bailey et al.. "-". . p. 785. Retrieved 1968.
• 2、 Bhattacherjee, Aditi,Sneha, Mahima,Lewis-Borrell, Luke,Amoruso, Giordano,Oliver, Thomas A.A.,Tyler, Jasper,Clark, Ian P.,Orr-Ewing, Andrew J.. "Singlet and Triplet Contributions to the Excited-State Activities of Dihydrophenazine, Phenoxazine, and Phenothiazine Organocatalysts Used in Atom Transfer Radical Polymerization". . p. 3613 - 3627. Retrieved 2021.
• 3、 Gannett, Cara N.,Peterson, Brian M.,Shen, Luxi,Seok, Jeesoo,Fors, Brett P.,Abru?a, Héctor D.. "Cross-linking Effects on Performance Metrics of Phenazine-Based Polymer Cathodes". . p. 2428 - 2435. Retrieved 2020.
• 4、 Zhang, Huanhuan,Tang, Xiaohui,Gu, Cheng. "Dihydrophenazine linked porous organic polymers for high capacitance and energy density pseudocapacitive electrodes and devices". . p. 4984 - 4989. Retrieved 2021.
• 5、 Gordienko,Chukhlontseva. "". . p. 616. Retrieved 1969.
• 6、 Kumar, Dhirendra,Chen, Yu-Lin,Tsai, Chih-Hung,Wong, Ken-Tsung. "Dihydrophenazine-based double-anchoring dye for dye-sensitized solar cells". . p. 361 - 369. Retrieved 2020.
• 7、 Jiang, Wei-Ling,Huang, Bin,Wu, Meng-Xiang,Zhu, Ye-Kai,Zhao, Xiao-Li,Shi, Xueliang,Yang, Hai-Bo. "Post-Synthetic Modification of Metal-Organic Frameworks Bearing Phenazine Radical Cations for aza-Diels-Alder Reactions". supporting information. p. 3985 - 3992. Retrieved 2021/11/01.