Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane)

Base Information

• Chemical Name: Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane)
• CAS No.: 52615-19-7
• Molecular Formula: C₃₁H₂₂Co₂O₆P₂
• Molecular Weight: 670.446
• Mol file: 52615-19-7.mol

Synonyms:Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane)

Chemical Property of Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane)

There total 13 articles about Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

{Co2(μ-CH2)(μ-CHCO2Et)(CO)4(μ-dppm)} → Ketene (463-51-4) + Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane) (52615-19-7) + Ketencarbonsaeure-aethylester

Guidance literature:

With carbon monoxide; In neat (no solvent); pyrolysis under CO atmosphere at 25°C;; not isolated; detected by NMR spectroscopy; ketenes trapped by reaction with CD3OD with formation of the corresponding esters;;

Reference yield: 80.0%

{Co2(μ-CHCH3)2(CO)4(μ-dppm)} → Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane) (52615-19-7) + prop-1-en-1-one (6004-44-0)

Guidance literature:

With carbon monoxide; In neat (no solvent); pyrolysis under CO atmosphere at 25°C;; not isolated; detected by NMR spectroscopy; ketene trapped by reaction with CD3OD with formation of the corresponding ester;;

Reference yield: 80.0%

{Co2(μ-CH2)2(CO)4(μ-dppm)} → Ketene (463-51-4) + Co2(CO)4(μ-CO)2(μ-bis(diphenylphosphino)methane) (52615-19-7)

Guidance literature:

With carbon monoxide; In neat (no solvent); pyrolysis under CO atmosphere at 25°C;; not isolated; detected by NMR spectroscopy; ketene trapped by reaction with CD3OD with formation of the corresponding ester;;

upstream raw materials:

dicobalt octacarbonyl

bis-diphenylphosphinomethane

Refernces

• 1、 Chang, Yu-Chang,Lee, Jian-Cheng,Hong, Fung-E.. "Design, synthesis, application, and DFT investigation of Suzuki-Miyaura reactions of a dicobalt carbonyl-containing phosphine ligand". . p. 5686 - 5695. Retrieved 2008/10/09.
• 2、 Lisic, Edward C.,Hanson, Brian E.. "Solution structure and dynamics of Co2(CO)6(L L) and Co4(CO)8(L L)2 molecules". . p. 812 - 815. Retrieved 2008/10/08.