Methane-13C, tetrachloro-

Base Information

• Chemical Name: Methane-13C, tetrachloro-
• CAS No.: 32488-50-9
• Molecular Formula: CCl4
• Molecular Weight: 154.812
• European Community (EC) Number: 686-128-3
• DSSTox Substance ID: DTXSID10108804
• Nikkaji Number: J1.770.077D
• Mol file: 32488-50-9.mol

Synonyms:Carbon-13C tetrachloride;32488-50-9;Methane-13C, tetrachloro-;Carbon tetrachloride-13C;tetrachloro(113C)methane;DTXSID10108804;AKOS015913548;Carbon-13C tetrachloride, 99 atom % 13C

Chemical Property of Methane-13C, tetrachloro-

Chemical Property:

• Melting Point: -23 °C
• Refractive Index: n20/D 1.46(lit.)
• Boiling Point: 76-77 °C
• PSA: 0.00000
• Density: 1.604 g/cm³
• LogP: 2.55290
• XLogP3: 2.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 154.875815
• Heavy Atom Count: 5
• Complexity: 19.1

Purity/Quality:

99% ^*data from raw suppliers

Carbon-13C tetrachloride 99 atom % ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 23/24/25-40-48/23-52/53-59
• Safety Statements: 23-36/37-45-59-61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(Cl)(Cl)(Cl)Cl
• Isomeric SMILES: [13C](Cl)(Cl)(Cl)Cl

Technology Process of Methane-13C, tetrachloro-

There total 1 articles about Methane-13C, tetrachloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

[13C]methanol (14742-26-8) → [(13)C]carbon tetrachloride (32488-50-9)

Guidance literature:

With chlorine; Irradiation;

DOI:10.1063/1.462279

Reference yield: 80.0%

[bis(triphenylphosphoranylidene)iminium][Rh(CO)4] (74364-66-2) + [(13)C]carbon tetrachloride (32488-50-9) → 2N(P(C6H5)3)2(1+)*Rh6(13)C(CO)15(2-)=(N(P(C6H5)3)2)2(Rh6(CO)15(13)C)

Guidance literature:

In methanol; (13)CCl4 added to MeOH soln. of Rh-complex; filtered, recrystd. from acetone-i-PrOH;

DOI:10.1039/DT9820001499

Reference yield: 45.0%

[(13)C]carbon tetrachloride (32488-50-9) + 5-phenyl-1-pentanal (36884-28-3) → C10(13)CH12Cl2 (1048681-66-8)

Guidance literature:

[⁽¹³⁾C]carbon tetrachloride; With triphenylphosphine; In tetrahydrofuran; for 1h; Inert atmosphere;

With magnesium; 1,2-dichloro-ethane; In tetrahydrofuran; for 0.416667h; Inert atmosphere;

5-phenyl-1-pentanal; In tetrahydrofuran; for 18.75h; Inert atmosphere;

DOI:10.1021/ja803106z

upstream raw materials:

[¹³C]methanol

Downstream raw materials:

carbon dioxide

<¹³C>-phosgene

1,2-(13)C2-tetrachloroethylene

rhenium(I) pentacarbonyl chloride

Refernces