1,3-Bis(phosphino)propane

Base Information

• Chemical Name: 1,3-Bis(phosphino)propane
• CAS No.: 3619-91-8
• Molecular Formula: C3H10 P2
• Molecular Weight: 108.06
• Hs Code.: 2901100000
• DSSTox Substance ID: DTXSID20402628
• Nikkaji Number: J1.119.702G
• Wikidata: Q82206057
• Mol file: 3619-91-8.mol

Synonyms:1,3-BIS(PHOSPHINO)PROPANE;3619-91-8;3-phosphanylpropylphosphane;Phosphine,1,3-propanediylbis- (9CI);(3-phosphanylpropyl)phosphane;Trimethylenebisphosphine;1,3-diphosphinopropane;1,3-Bis-phosphanyl-propane;SCHEMBL1323055;DTXSID20402628;AKOS006295179;FT-0690888;A874405

Chemical Property of 1,3-Bis(phosphino)propane

Chemical Property:

• Boiling Point: 129-131 °C(Press: 725 Torr)
• PSA: 27.18000
• Density: 0.877 g/cm3
• LogP: 1.12670
• XLogP3: -0.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 108.02577431
• Heavy Atom Count: 5
• Complexity: 12.4

Purity/Quality:

98% ^*data from raw suppliers

1,3-BIS(PHOSPHINO)PROPANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(CP)CP

Technology Process of 1,3-Bis(phosphino)propane

There total 6 articles about 1,3-Bis(phosphino)propane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

phosphan (7803-51-2) + 1,3-Dichloropropane (142-28-9) → 1,3-bisphosphinopropane (3619-91-8)

Guidance literature:

With potassium hydroxide; In Petroleum ether; at 20 ℃; for 1h;

Reference yield: 75.0%

phosphan (7803-51-2) + 1,3-dibromo-propane (109-64-8) → 1,3-bisphosphinopropane (3619-91-8)

Guidance literature:

With potassium hydroxide; In dimethyl sulfoxide; at 20 ℃; for 2h;

Reference yield: 65.0%

1,3-bis(diethoxyphosphinyl)propane (22401-25-8) → 1,3-bisphosphinopropane (3619-91-8)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; for 72h; Ambient temperature;

upstream raw materials:

1,3-Dichloropropane

phosphan

1,3-dibromo-propane

1,3-bis(diethoxyphosphinyl)propane

Downstream raw materials:

1,3-Propandiylbis(dichlorphosphan)

Refernces

• 1、 Bianco,V.D.,Doronzo,S.. "-". . p. 431 - 433. Retrieved 1971.
• 2、 Berven, Bradley M.,Koutsantonis, George A.. "Highly fluorous bidentate phosphines". body text. p. 2626 - 2630. Retrieved 2009/04/06.
• 3、 Alder, Roger W.,Ganter, Christian,Gil, Michelle,Gleiter, Rolf,Harris, Christopher J.,et al.. "Medium-ring diphosphines from diphosphabicycloalkanes: stereoselective syntheses, structure and properties". . p. 1643 - 1656. Retrieved 2007/10/03.