5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo

Base Information

• Chemical Name: 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo
• CAS No.: 115775-87-6
• Molecular Formula: C₅₆H₅₂MnN₄O
• Molecular Weight: 851.993
• Mol file: 115775-87-6.mol

Synonyms:5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo

Chemical Property of 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo

There total 7 articles about 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

tetramethyl ammonium hydroxide + (5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo (115775-87-6)

Guidance literature:

In methanol; dichloromethane; after cooling to 0°C addn. of m-CPBA, stirring for 1min at 0°C; chromy. at -78°C on a basic alumina column (CH2Cl2/ethyl acetate 1:1), evapn. of the solvent at -78°C and drying of the precipitate in vac. at room temp.;

DOI:10.1021/ja00234a009

Reference yield:

(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7) → 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo (115775-87-6)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In acetonitrile; at -40.16 ℃;

DOI:10.1021/ja9045235

Reference yield:

[MnIII(5,10,15,20-tetramesityphenylporphyrin)(ClO3)] → 5,10,15,20-tetramesitylporphyrin?manganese(IV)-oxo (115775-87-6)

Guidance literature:

In acetonitrile; at 23 ℃; Irradiation;

DOI:10.1016/j.jinorgbio.2019.110986

upstream raw materials:

lithium hypochlorite

(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride

3-chloro-benzenecarboperoxoic acid

1-(tert-butylsulfonyl)-2-iodosylbenzene

Downstream raw materials:

hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

benzyl chloride

1-bromocyclohexane

benzyl bromide

Refernces

• 1、 Lee, Robert W.,Nakagaki, Paul C.,Bruice, Thomas C.. "The Kinetics for the Reaction of Hypochlorite with a Manganese(III) Porphyrin and Subsequent Epoxidation of Alkenes in a Homogeneous Solution". . p. 1368 - 1372. Retrieved 1989.
• 2、 Klaine, Seth,Bratcher, Fox,Winchester, Charles M.,Zhang, Rui. "Formation and kinetic studies of manganese(IV)-oxo porphyrins: Oxygen atom transfer mechanism of sulfide oxidations". . . Retrieved 2020/01/08.
• 3、 Takai, Atsuro,Habermeyer, Benoit,Fukuzumi, Shunichi. "Facile formation of a meso-meso linked porphyrin dimer catalyzed by a manganese(iv)-oxo porphyrin". scheme or table. p. 6804 - 6806. Retrieved 2011/08/22.