CID 11095625

Base Information

• Chemical Name: CID 11095625
• CAS No.: 41593-58-2
• Molecular Formula: C12H14 B P
• Molecular Weight: 200.028
• Hs Code.: 29310099
• European Community (EC) Number: 627-404-5
• DSSTox Substance ID: DTXSID80455019
• Mol file: 41593-58-2.mol

Synonyms:41593-58-2;diphenylphosphane boron;diphenylphosphine borane;diphenylphosphine-borane;SCHEMBL184292;DTXSID80455019;LRNNYBXLESRLOS-UHFFFAOYSA-N;XUFGOLYVDOBYLK-UHFFFAOYSA-N;MFCD00274254;CID 11095625;FT-0757885;F14999

Chemical Property of CID 11095625

Chemical Property:

• Melting Point: 47-50 °C(lit.)
• Boiling Point: 148-150 °C10 mm Hg(lit.)
• PSA: 13.59000
• LogP: 1.13200
• Storage Temp.: water-free area
• Sensitive.: Moisture Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 197.0691425
• Heavy Atom Count: 14
• Complexity: 116

Purity/Quality:

99% ^*data from raw suppliers

Borane diphenylphosphine complex 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 15
• Safety Statements: 43

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [B].C1=CC=C(C=C1)PC2=CC=CC=C2
• Uses: Reactant for:Nucleophilic addition reactions (anion)Catalytic dehydrogenation in the presence of ruthenium bidentate phosphine compelxesDeprotonation reactionsCatalytic coupling with alkynyl bromidesCatalyst-free Staudinger ligation for indirect 18F-radiolabelingPreparation of chiral phosphine-phosphite bidentate ligands with biphenyl backboneReactions with frustrated lewis pair combinations of group 14 triflates and sterically hindered nitrogen bases

Technology Process of CID 11095625

There total 24 articles about CID 11095625 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

diphenylphosphane (829-85-6) → diphenylphosphineborane (41593-58-2)

Guidance literature:

With borane-THF; In tetrahydrofuran; for 7h; Inert atmosphere;

DOI:10.1016/j.tetlet.2011.11.043

Reference yield: 95.0%

sodium tetrahydroborate (16940-66-2) + diphenylphosphane (829-85-6) → diphenylphosphineborane (41593-58-2)

Guidance literature:

With carbon dioxide; In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1039/d1dt03495b

Reference yield: 95.0%

borane-THF (14044-65-6) + diphenylphosphane (829-85-6) → diphenylphosphineborane (41593-58-2)

Guidance literature:

In tetrahydrofuran; at -78 ℃; for 16h; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.organomet.7b00326

upstream raw materials:

diphenylphosphane

Diphenylphosphine oxide

sodium tetrahydroborate

phenylphosphine-borane

Downstream raw materials:

diphenylcyclohexylphosphine-borane complex

Ph₂P(BH₃)CH(OH)C₆H₄Cl-p

(C₆H₅)2P(BH₃)(C₆H₉O)

(C₆H₅)2P(BH₃)CH(C₆H₅)CH₂CHO

Refernces

• 1、 Landais, Yannick,Laye, Claire,Lusseau, Jonathan,Robert, Frédéric. "The Trityl-Cation Mediated Phosphine Oxides Reduction". . p. 3035 - 3043. Retrieved 2021/05/10.
• 2、 Hamann, Henry J.,Lin, Randy,Veeraraghavan Ramachandran, P.. "Activation of sodium borohydride via carbonyl reduction for the synthesis of amine- And phosphine-boranes". supporting information. p. 16770 - 16774. Retrieved 2021/12/08.