Mn(IV)(O)(OH)(tetramesitylporphyrin)

Base Information

• Chemical Name: Mn(IV)(O)(OH)(tetramesitylporphyrin)
• CAS No.: 108535-08-6
• Molecular Formula: C₅₆H₅₃MnN₄O₂
• Molecular Weight: 869
• Mol file: 108535-08-6.mol

Synonyms:Mn(IV)(O)(OH)(tetramesitylporphyrin)

Chemical Property of Mn(IV)(O)(OH)(tetramesitylporphyrin)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mn(IV)(O)(OH)(tetramesitylporphyrin)

There total 9 articles about Mn(IV)(O)(OH)(tetramesitylporphyrin) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

tetra-n-butylammonium hydroxide + (5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7) → hydroxo-oxo(5,10,15,20-tetramesitylporphyrinato)manganese(IV) (108535-08-6)

Guidance literature:

With TBAP; In dichloromethane; Electrolysis; electrolysis at +1.20 V, pipeting of react. soln. in -78°C pentane and standing for 5 min; filtering and chromy. (basic alumina) at -78°C, evapn. of the solvent, vac. drying of the solid at low temp.;

DOI:10.1021/ja00234a009

Reference yield:

(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride (85939-49-7) → Mn(IV)(O)(OH)(tetramesitylporphyrin) (108535-08-6)

Guidance literature:

With tetramethyl ammoniumhydroxide; 3-chloro-benzenecarboperoxoic acid; In methanol; dichloromethane; 0°C, 2 equivalents Me4NOH in MeOH, TBA(OH) added, stirred for 3 min.; Alumina chromatography, -78°C.;

DOI:10.1021/ja00221a010

Reference yield:

ClMn(III)(tetramesitylporphyrin) cation radical (104025-52-7) → Mn(IV)(O)(OH)(tetramesitylporphyrin) (108535-08-6)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In dichloromethane; water; Addn. of TBA(OH) soln. (40% in H2O) to soln. of complex at -20°C.; not isolated, detn. by UV/VIS spectroscopy;

DOI:10.1021/ja00221a010

upstream raw materials:

(5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride

ClMn(III)(tetramesitylporphyrin) cation radical

hydroxo(5,10,15,20-tetramesitylporphyrinato)manganese(III)

3-chloro-benzenecarboperoxoic acid

Refernces

• 1、 Czernuszewicz,Y. Oliver,Stern,Macor,Kim,Groves,Spiro. "OXOMANGANESE(IV) PORPHYRINS IDENTIFIED BY RESONANCE RAMAN AND INFRARED SPECTROSCOPY: WEAK BONDS AND THE STABILITY OF THE HALF-FILLED T2g SUBSHELL.". . p. 4158 - 4165. Retrieved 2007/10/02.