Methyl beta-D-xylofuranoside

Base Information

• Chemical Name: Methyl beta-D-xylofuranoside
• CAS No.: 1824-97-1
• Molecular Formula: C6H12 O5
• Molecular Weight: 164.158
• Nikkaji Number: J1.502.885H
• Mol file: 1824-97-1.mol

Synonyms:1824-97-1;Methyl b-D-xylofuranoside;.BETA.-D-XYLOFURANOSIDE, METHYL;Methyl beta-D-xylofuranoside;(2R,3R,4R,5R)-2-(HYDROXYMETHYL)-5-METHOXYOXOLANE-3,4-DIOL;SCHEMBL14856334

Chemical Property of Methyl beta-D-xylofuranoside

Chemical Property:

• Melting Point: 45 °C
• Boiling Point: 348.7±42.0 °C(Predicted)
• PKA: 13.14±0.70(Predicted)
• Density: 1.40
• XLogP3: -1.6
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 2
• Exact Mass: 164.06847348
• Heavy Atom Count: 11
• Complexity: 128

Purity/Quality:

98%,99%, ^*data from raw suppliers

Methyl b-D-xylofuranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: COC1C(C(C(O1)CO)O)O
• Isomeric SMILES: CO[C@H]1[C@@H]([C@H]([C@H](O1)CO)O)O

Technology Process of Methyl beta-D-xylofuranoside

There total 37 articles about Methyl beta-D-xylofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + D-Ribose (532-20-7,613-83-2,7261-25-8,7687-39-0,13221-22-2,14795-83-6,15761-67-8,20074-49-1,25545-03-3,25545-04-4,32445-75-3,34436-17-4,36441-93-7,36468-53-8,37110-85-3,37388-49-1,38029-69-5,40461-77-6,40461-89-0,41546-19-4,41546-20-7,41546-21-8,41546-26-3,41546-29-6,41546-30-9,41546-31-0,126872-16-0,131064-98-7) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With Dowex-50 (H+); at 4 ℃;

DOI:10.1002/ejoc.200600182

Reference yield: 100.0%

methanol (67-56-1) + D-ribose (50-69-1) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With Dowex-50w (H⁺); at 0 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.bmc.2010.07.005

Reference yield: 79.0%

methanol (67-56-1) + C30H26N4O8 (189129-08-6) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With sodium methylate; for 0.75h; Ambient temperature; other reagent, reaction time;

DOI:10.1080/07328319708002528

upstream raw materials:

methanol

D-xylose

Methyl 3,5-O-Isopropylidene-β-D-xylofuranoside

D-xylofuranose

Downstream raw materials:

[6-methoxy-2-(4-methoxyphenyl)tetrahydrofuro[3,4-d][1,3]-dioxol-4-yl]methanol

2,3,5-tri-O-benzoyl-D-ribofuranosyl bromide

2',3',5'-tri-O-[3-(trifluoromethyl)benzoyl]-5-methyluridine

2',3',5'-tri-O-[3-(trifluoromethyl)benzoyl]uridine

Refernces

• 1、 -. "MODIFIED OLIGOMERIC COMPOUNDS AND USES THEREOF". Page/Page column 119-121. . Retrieved 2021/02/19.
• 2、 -. "Novel saccharide bio-based cyclic phosphorus/phosphonate as well as preparation method and application thereof". Paragraph 0039; 0041-0042. . Retrieved 2021/09/04.