Zirconium dichloride oxide hydrate

Base Information

• Chemical Name: Zirconium dichloride oxide hydrate
• CAS No.: 15461-27-5
• Molecular Formula: Cl₂OZr*8H₂O
• Molecular Weight: 322.252
• Hs Code.: 28274990
• European Community (EC) Number: 628-572-2
• Mol file: 15461-27-5.mol

Synonyms:15461-27-5;Zirconyl chloride hydrate;Zirconium dichloride oxide hydrate;oxozirconium;hydrate;dihydrochloride;Zirconium(IV)dichlorideoxide hydrate;MFCD00149897;Zirconium, dichlorooxo-, monohydrate;Zirconium(IV) dichloride oxide hydrate;oxozirconium(IV) chloride hydrate;AKOS028109267;Zirconyl chloride hydrate, 99.99% trace metals basis;Zirconium(IV) dichloride oxide hydrate (99.99+%-Zr) PURATREM

Chemical Property of Zirconium dichloride oxide hydrate

Chemical Property:

• Melting Point: 400 °C
• PSA: 26.30000
• Density: 1.910
• LogP: 1.19590
• Water Solubility.: Soluble in cold water, methanol, diethyl ether and alcohol.Slightly soluble in hydrochloric acid. Insoluble in organic solvents.
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 195.863534
• Heavy Atom Count: 5
• Complexity: 6

Purity/Quality:

98%,99%, ^*data from raw suppliers

Zirconium(IV) dichloride oxide hydrate (99.9%-Zr) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45-7/8

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: O.O=[Zr].Cl.Cl
• Uses: Zirconium dichloride oxide hydrate is used as a precursor for the manufacturing of other zirconium salts. It is also used in textile dyeing, oil-field acidizing, antiperspirants, water repellents and in titanium dioxide pigment coatings.

Technology Process of Zirconium dichloride oxide hydrate

There total 1 articles about Zirconium dichloride oxide hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + zirconium(IV) carbonate → ziconium(IV) oxychloride octahydrate (13520-92-8,25399-81-9,15461-27-5)

Guidance literature:

In hydrogenchloride; byproducts: CO2; Zr(CO3)2 dissolved in concd. HCl, refluxed for 1 h; cooled, filtered, washed with cold concd. HCl, recrystd. from aq. HCl, air dried;

DOI:10.1021/ic50217a054

Reference yield: 86.0%

ziconium(IV) oxychloride octahydrate (13520-92-8,25399-81-9,15461-27-5) + 2,4,6-tris[4-(phosphonomethyl)phenyl]-1,3,5-triazine + water (7732-18-5) → Zr(H4ttbmp)2*10H2O

Guidance literature:

With hydrogen fluoride; In methanol; at 80 ℃; for 48h;

DOI:10.1039/c4cc06223j

Reference yield: 72.0%

ziconium(IV) oxychloride octahydrate (13520-92-8,25399-81-9,15461-27-5) + formic acid (64-18-6) + 4,4',4'',4'''-((4,4',4'',4'''-(porphyrin-5,10,15,20-tetrayl)tetrakis(benzoyl))tetrakis(azanediyl))tetrabenzoic acid + N,N-dimethyl-formamide (68-12-2,33513-42-7) → [Zr6(μ3-O)4(μ3-OH)4(OH)4(H2O)4](L)2*12H2O*45(N,N-dimethylformamide)*33HCOOH

Guidance literature:

at 120 ℃; for 48h; Autoclave;

DOI:10.1002/chem.201600447

upstream raw materials:

hydrogenchloride

Refernces