1-Bromo-2-methoxy-2-methylpropane

Base Information

• Chemical Name: 1-Bromo-2-methoxy-2-methylpropane
• CAS No.: 19752-21-7
• Molecular Formula: C5H11BrO
• Molecular Weight: 167.046
• European Community (EC) Number: 815-749-6
• DSSTox Substance ID: DTXSID50448332
• Nikkaji Number: J529.516E
• Wikidata: Q82267303
• Mol file: 19752-21-7.mol

Synonyms:1-bromo-2-methoxy-2-methylpropane;19752-21-7;2-METHOXY-2-METHYLPROPYL BROMIDE;1-bromo-2-methoxy-2-methyl-propane;MFCD08063237;Propane, 1-bromo-2-methoxy-2-methyl-;Propane,1-bromo-2-methoxy-2-methyl-;SCHEMBL3191459;DTXSID50448332;BBL103492;STL557302;AKOS006284234;AM806263;BS-12760;SY007681;CS-0037745;EN300-134530;A919540

Chemical Property of 1-Bromo-2-methoxy-2-methylpropane

Chemical Property:

• Boiling Point: 141.617 °C at 760 mmHg
• Flash Point: 50.552 °C
• PSA: 9.23000
• Density: 1.278 g/cm³
• LogP: 1.80630
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 165.99933
• Heavy Atom Count: 7
• Complexity: 52

Purity/Quality:

99% ^*data from raw suppliers

1-bromo-2-methoxy-2-methylpropane ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(CBr)OC

Technology Process of 1-Bromo-2-methoxy-2-methylpropane

There total 3 articles about 1-Bromo-2-methoxy-2-methylpropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

→ 1-bromo-2-methoxy-2-methylpropane (19752-21-7)

Guidance literature:

Reference yield:

methanol (67-56-1) + isobutene (115-11-7,15220-85-6) → 1,2-dibromo-2-methyl-propane (594-34-3) + 1-bromo-2-methoxy-2-methylpropane (19752-21-7)

Guidance literature:

With sodium bromide; In methanol; at 25 ℃; Product distribution; electrolysis; regio- and chemoselectivity of bromination; other gem-dialkylalkenes;

DOI:10.1021/jo00059a051

Reference yield:

methanol (67-56-1) + isobutene (115-11-7,15220-85-6) → 1-bromo-2-methoxy-2-methylpropane (19752-21-7)

Guidance literature:

With sodium bromide; (electrolysis);

DOI:10.1021/ja00479a035

upstream raw materials:

methanol

isobutene

Downstream raw materials:

2-methoxyisobutyl amine

Refernces

• 1、 -. "Method for synthesis and 99m C labelling of 2-alkoxyisobutylisonitrile". . . Retrieved 2008/06/13.