BORANE-DICYCLOHEXYLPHOSPHINE COMPLEX

Base Information

• Chemical Name: BORANE-DICYCLOHEXYLPHOSPHINE COMPLEX
• CAS No.: 108756-88-3
• Molecular Formula: C12H26BP
• Molecular Weight: 212.123
• Hs Code.: 29310099
• Mol file: 108756-88-3.mol

Synonyms:DICYCLOHEXYLPHOSPHINE BORANE COMPLEX;BORANE-DICYCLOHEXYLPHOSPHINE COMPLEX

Chemical Property of BORANE-DICYCLOHEXYLPHOSPHINE COMPLEX

Chemical Property:

• Melting Point: 77-81 °C
• PSA: 13.59000
• LogP: 3.14640
• Storage Temp.: water-free area

Purity/Quality:

99% ^*data from raw suppliers

DICYCLOHEXYLPHOSPHINE BORANE COMPLEX 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F
• Statements: 15
• Safety Statements: 43A

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of BORANE-DICYCLOHEXYLPHOSPHINE COMPLEX

There total 12 articles about BORANE-DICYCLOHEXYLPHOSPHINE COMPLEX which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dimethylsulfide borane complex (13292-87-0) + dicyclohexylphosphane (829-84-5) → (dicyclohexylphosphino)borane (108756-88-3)

Guidance literature:

In diethyl ether; at 5 - 10 ℃; for 0.166667h; Cooling with ice;

Reference yield: 94.7%

dicyclohexylphosphane (829-84-5) → (dicyclohexylphosphino)borane (108756-88-3)

Guidance literature:

With sodium tetrahydroborate; acetic acid; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1016/j.tetlet.2003.10.145

Reference yield: 90.0%

borane-THF (14044-65-6) + dicyclohexylphosphane (829-84-5) → (dicyclohexylphosphino)borane (108756-88-3)

Guidance literature:

In tetrahydrofuran; (Ar), borane tetrahydrofuran soln. slowly addn. to dicyclohexylphosphinesoln. (273 K), stirring (273 K, 2 h), warming (room temp.), crystn. on evapn.; recrystn. (pentane);

DOI:10.1107/S0108270196010050

upstream raw materials:

dicyclohexylphosphane

dicyclohexylphosphine oxide

borane-THF

Cy₂PH*GaH₃

Downstream raw materials:

(C₆H₁₁)2P(BH₃)C₅H₉NCH₃

2-(boranatodicyclohexylphosphino)fluorobenzenetricarbonylchromium

dicyclohexyl(4-phenylcyclohexyl)phosphine-borane

C₃₃H₅₅BOP₂

Refernces

• 1、 Day, Michael W.,Mohr, Bernhard,Grubbs, Robert H.. "(Dicyclohexylphosphino)borane, BH3PH(C6H11)2, a precursor to water-soluble phosphine ligands". . p. 3106 - 3108. Retrieved 1996.
• 2、 -. "N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE-BORANE COMPLEX AND PRODUCTION METHOD THEREFOR, AND METHOD FOR PRODUCING RUTHENIUM COMPLEX CONTAINING N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE AS LIGAND". Paragraph 0106; 0115-0120. . Retrieved 2019/02/19.