10-Undecen-1-yl acetate

Base Information

• Chemical Name: 10-Undecen-1-yl acetate
• CAS No.: 112-19-6
• Molecular Formula: C13H24 O2
• Molecular Weight: 212.332
• Hs Code.: 2915390090
• European Community (EC) Number: 203-944-3
• NSC Number: 525
• UNII: 7DOE964C4L
• DSSTox Substance ID: DTXSID80861737
• Nikkaji Number: J22.114G
• Wikidata: Q27268120
• Metabolomics Workbench ID: 44659
• Mol file: 112-19-6.mol

Synonyms:10-Undecen-1-yl acetate;Undec-10-enyl acetate;112-19-6;10-Undecenyl acetate;Undecenyl acetate;Acetate C-11;10-Undecen-1-ol acetate;10-UNDECEN-1-OL, ACETATE;1-Undecen-11-yl acetate;10-Hendecen-1-yl acetate;Undecylenyl acetate;10-Hendecenyl acetate;10-Undecen-1-ol, 1-acetate;FEMA No. 3096;NSC 525;EINECS 203-944-3;BRN 1769966;UNII-7DOE964C4L;10-Undecen-1-ol,1-acetate;AI3-03928;7DOE964C4L;NSC-525;n-UNDECYLENIC ACETATE;undec-10-en-1-yl acetate;Acetic acid 10-undecenyl;SCHEMBL541022;undec - 10 - enyl acetate;NSC525;WLN: 1VO10U1;1-ACETOXYUNDEC-10-ENE;FEMA 3096;DTXSID80861737;CHEBI:172455;ACETATE, 10-UNDECEN-1-YL;LS-3148;10-UNDECEN-1-YL ACETATE [FHFI];FT-0748175;Q27268120

Chemical Property of 10-Undecen-1-yl acetate

Chemical Property:

• Vapor Pressure: 0.0119mmHg at 25°C
• Melting Point: -69°C (estimate)
• Refractive Index: 1.4363 (estimate)
• Boiling Point: 261°Cat760mmHg
• Flash Point: 106.5°C
• PSA: 26.30000
• Density: 0.878g/cm³
• LogP: 3.85630
• XLogP3: 4.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 212.177630004
• Heavy Atom Count: 15
• Complexity: 164

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=O)OCCCCCCCCCC=C
• Uses: Perfumery, flavoring.

Technology Process of 10-Undecen-1-yl acetate

There total 22 articles about 10-Undecen-1-yl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

10-Undecen-1-ol (112-43-6) + acetic anhydride (108-24-7) → 10-undecenyl acetate (112-19-6)

Guidance literature:

With dmap; triethylamine; at 20 ℃; for 24h;

Reference yield: 95.0%

acetic anhydride (108-24-7) + 11-(methoxymethoxy)undec-1-ene (268218-81-1) → 10-undecenyl acetate (112-19-6)

Guidance literature:

With iron(III) chloride; In dichloromethane; at -30 ℃; for 3h;

DOI:10.1055/s-2000-6258

Reference yield: 93.0%

10-Undecen-1-ol (112-43-6) + acetylacetone (123-54-6,81235-32-7) → 10-undecenyl acetate (112-19-6)

Guidance literature:

indium(III) triflate; at 80 ℃; for 24h;

DOI:10.1002/anie.200702798

upstream raw materials:

10-Undecen-1-ol

acetic anhydride

9-undecenol

acetyl chloride

Downstream raw materials:

1,10-undecadiene

1-Bromo-11-hydroxyundecane

undecyl acetate

1,18-octadecamethylene diacetate

Refernces

• 1、 Marvel,Garrison. "-". . p. 4737,4741. Retrieved 1959.
• 2、 Boyer, Cyrille,Bulmus, Volga,Priyanto, Priyanto,Teoh, Wey Yang,Amal, Rose,Davis, Thomas P.. "The stabilization and bio-functionalization of iron oxide nanoparticles using heterotelechelic polymers". . p. 111 - 123. Retrieved 2009.
• 3、 Pirson et al.. "". . p. 16,17,18. Retrieved 1973.
• 4、 Molnár, István Gábor,Gilmour, Ryan. "Catalytic Difluorination of Olefins". . p. 5004 - 5007. Retrieved 2016.
• 5、 Kaiser, Daniel,Tona, Veronica,Gon?alves, Carlos R.,Shaaban, Saad,Oppedisano, Alberto,Maulide, Nuno. "A General Acid-Mediated Hydroaminomethylation of Unactivated Alkenes and Alkynes". supporting information. p. 14639 - 14643. Retrieved 2019/09/17.
• 6、 Tappin, Nicholas D. C.,Michalska, Weronika,Rohrbach, Simon,Renaud, Philippe. "Cyclopropanation of Terminal Alkenes through Sequential Atom-Transfer Radical Addition/1,3-Elimination". supporting information. p. 14240 - 14244. Retrieved 2019/08/26.