C₆₆H₈₁N₃O₂₈S

Base Information

• Chemical Name: C₆₆H₈₁N₃O₂₈S
• CAS No.: 898528-09-1
• Molecular Formula: C₆₆H₈₁N₃O₂₈S
• Molecular Weight: 1396.44
• Mol file: 898528-09-1.mol

Synonyms:C₆₆H₈₁N₃O₂₈S

Chemical Property of C₆₆H₈₁N₃O₂₈S

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of C₆₆H₈₁N₃O₂₈S

There total 2 articles about C₆₆H₈₁N₃O₂₈S which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.1%

6-aminohexyl [methyl(2,3-di-O-benzoyl-4-O-methyl-β-D-glucopyranosyl)uronate]-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranoside (898528-08-0) + dansylglycine (1091-85-6) → C66H81N3O28S (898528-09-1)

Guidance literature:

With diethyl cyanophosphonate; triethylamine; In N,N-dimethyl-formamide; at 20 ℃; for 16h;

DOI:10.1248/cpb.54.485

Reference yield:

6-N-(2,2,2-trichloroethoxycarbonyl)aminohexyl [methyl(2,3-di-O-benzoyl-4-O-methyl-β-D-glucopyranosyl)uronate]-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranoside (898528-07-9) → C66H81N3O28S (898528-09-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 76.9 percent / Zn; AcOH / 16 h / 20 °C

2: 68.1 percent / triethylamine; diethyl phosphorocyanidate / dimethylformamide / 16 h / 20 °C

With diethyl cyanophosphonate; acetic acid; triethylamine; zinc; In N,N-dimethyl-formamide;

DOI:10.1248/cpb.54.485

upstream raw materials:

6-aminohexyl [methyl(2,3-di-O-benzoyl-4-O-methyl-β-D-glucopyranosyl)uronate]-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranoside

dansylglycine

6-N-(2,2,2-trichloroethoxycarbonyl)aminohexyl [methyl(2,3-di-O-benzoyl-4-O-methyl-β-D-glucopyranosyl)uronate]-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranosyl)-(1->6)-2,3,4-tri-O-acetyl-β-D-galactopyranoside

Refernces