TETRAPROPYLAMMONIUM PERRUTHENATE

Base Information

• Chemical Name: TETRAPROPYLAMMONIUM PERRUTHENATE
• CAS No.: 114615-82-6
• Molecular Formula: C12H28NO4Ru
• Molecular Weight: 351.429
• Hs Code.: 28439000
• Mol file: 114615-82-6.mol

Synonyms:TETRAPROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII);TPAP;Tetrapropylammoniumperruthenate,min.97%TPAP;1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-);Tetrapropylammonium Perruthenate (TPAP);Tetra-n-propylammonium perruthenate(VII), 98+%

Chemical Property of TETRAPROPYLAMMONIUM PERRUTHENATE

Chemical Property:

• Melting Point: ~160 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 74.27000
• Density: g/cm³
• LogP: 2.96800
• Storage Temp.: 2-8°C
• Sensitive.: Hygroscopic
• Solubility.: Methanol (Slightly)
• Water Solubility.: Insoluble in water.

Purity/Quality:

99% min ^*data from raw suppliers

Tetrapropylammonium Perruthenate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: O,Xi
• Statements: 5-8-36/37/38
• Safety Statements: 17-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Uses: A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones. Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.

Technology Process of TETRAPROPYLAMMONIUM PERRUTHENATE

There total 8 articles about TETRAPROPYLAMMONIUM PERRUTHENATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.7%

rhodium(III) chloride hydrate + tetrapropylammonium hydroxide (4499-86-9) → tetrapropylammonium perruthennate (114615-82-6)

Guidance literature:

rhodium(III) chloride hydrate; With sodium bromate; sodium carbonate; In water; at 30 - 40 ℃; for 5h;

tetrapropylammonium hydroxide; at 30 ℃; for 5h; Temperature;

Reference yield: 99.0%

sodium bromate + ruthenium trichloride hydrate (14898-67-0) + tetrapropylammonium hydroxide → tetrapropylammonium perruthennate (114615-82-6)

Guidance literature:

With sodium carbonate; In water; mixt. of RuCl3 and NaBrO3, Na2CO3 in water stirred until color changed to yellow green, addn. of n-Pr4NOH with stirring, deep green pptn.; extd. with alcohol free CH2Cl2, dried over anhydrous Na2CO3, concd. in vac., recrystd. from CCl4; elem. anal.;

Reference yield: 96.0%

ruthenium tetroxide (20427-56-9) + tetrapropylammonium hydroxide → tetrapropylammonium perruthennate (114615-82-6)

Guidance literature:

With K₂CO₃; stirred at 0°C for 3 h; washed with ice-cold H2O, dried in vac.; elem. anal.;

upstream raw materials:

ruthenium trichloride hydrate

sodium periodate

ruthenium tetroxide

tetrapropylammonium hydroxide

Downstream raw materials:

1-(3-Methoxymethoxy-2-oxo-butyl)-2-oxo-6-m-tolyl-4-trifluoromethyl-1,2-dihydro-pyridine-3-carbonitrile

1-{4[1-(3-Fluoro-benzyl)-1H-indazol-5-ylamino]-pyrrolo[2,1-f][1,2,4]triazin-5-ylmethyl}-pyrrolidin-3-one

4-cyclohexylamino-3-nitrobenzaldehyde

4-[5-(4-Phenylbutyl)-1,2,4-oxadiazol-3-yl]benzaldehyde

Refernces

• 1、 Dallaston, Madeleine A.,Bettencourt, Christian J.,Chow, Sharon,Gebhardt, Joshua,Spangler, Jordan,Johnston, Martin R.,Wall, Craig,Brusnahan, Jason S.,Williams, Craig M.. "Ranking Oxidant Sensitiveness: A Guide for Synthetic Utility". . p. 9614 - 9618. Retrieved 2019.
• 2、 -. "Preparation method of tetra-n-propyl ammonium perruthenium". Paragraph 0011-0018. . Retrieved 2021/02/06.